Cyclopolymers as liquid membrane carriers

被引：17
作者：
Cagnoni, E
Pasini, D
Galbiati, A
Ricci, M
Righetti, PP
机构：
[1] Univ Pavia, Dipartimento Chim Organ, I-27100 Pavia, Italy
[2] NPT Srl, I-27027 Gropello Cairoli, PV, Italy
来源：
MACROMOLECULES | 2003年 / 36卷 / 23期
关键词：
D O I：
10.1021/ma034901e
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
An overview is given of the synthesis of novel cyclocopolymers bearing oligoethylene glycol substituents in the form of malonate crown ethers embedded within a rigid polymer backbone. Both monomers and polymers show recognition and selectivity behavior for alkaline metal ions as their picrate salts and can be used as liquid membrane carriers for those ions. The ion selectivity is severely modified when the crown ethers are polymerized.
引用
收藏
页码：8894 / 8897
页数：4
相关论文
共 41 条
  • [1] Backinowsky LV, 2002, CHEM-EUR J, V8, P4412, DOI 10.1002/1521-3765(20021004)8:19<4412::AID-CHEM4412>3.0.CO
  • [2] 2-F
  • [3] Synthesis and liquid membrane transport properties of photolabile molecular clips based on dithiane-spiro-crown ethers
    Barnhurst, LA
    Kutateladze, AG
    [J]. ORGANIC LETTERS, 2001, 3 (17) : 2633 - 2635
  • [4] Alkali metal cation cooperative iodide anion recognition by new heteroditopic bis(calix[4]arene) rhenium(I) bipyridyl receptor molecules
    Beer, PD
    Cooper, JB
    [J]. CHEMICAL COMMUNICATIONS, 1998, (01) : 129 - 130
  • [5] Synthesis and biological activity of 4-amino-7-oxo-substituted analogues of 5-deaza-5,6,7,8-tetrahydrofolic acid and 5,10-dideaza-5,6,7,8-tetrahydrofolic acid
    Borrell, JI
    Teixidó, J
    Martínez-Teipel, B
    Matallana, JL
    Copete, MT
    Llimargas, A
    García, E
    [J]. JOURNAL OF MEDICINAL CHEMISTRY, 1998, 41 (18) : 3539 - 3545
  • [6] THE SYNTHESIS OF SOME SUBSTITUTED MACROCYCLIC POLYETHER-DIESTER COMPOUNDS WITH THE MALONYL MOIETY
    BRADSHAW, JS
    JOLLEY, ST
    JONES, BA
    [J]. JOURNAL OF HETEROCYCLIC CHEMISTRY, 1980, 17 (06) : 1317 - 1318
  • [7] PREPARATION OF MACROCYCLIC ETHER-ESTERS, THIOETHER-ESTERS, AND ETHER-THIOLESTERS
    BRADSHAW, JS
    BISHOP, CT
    NIELSEN, SF
    ASAY, RE
    MASIHDAS, DRK
    FLANDERS, ED
    HANSEN, LD
    IZATT, RM
    CHRISTENSEN, JJ
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1976, (23): : 2505 - 2508
  • [8] Crown ethers: The search for selective ion ligating agents
    Bradshaw, JS
    Izatt, RM
    [J]. ACCOUNTS OF CHEMICAL RESEARCH, 1997, 30 (08) : 338 - 345
  • [9] Butler GB, 2000, J POLYM SCI POL CHEM, V38, P3451, DOI 10.1002/1099-0518(20001001)38:19<3451::AID-POLA10>3.0.CO
  • [10] 2-N
12345