Aggregation of Aeromonas gum in aqueous solution

被引:17
作者
Zhang, L [1 ]
Xu, XJ
Jiang, GW
Iijima, H
Tsuchiya, H
机构
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Asahi Chem Ind Co Ltd, Chem Technol Dept 4, Miyazaki 8820847, Japan
[3] Asahi Chem Ind Co Ltd, Specialty Chem Sales Dept 4, Tokyo 1008440, Japan
关键词
aggregation; Aeromonas gum; light scattering; viscometry; polysaccharide aqueous solution;
D O I
10.1295/polymj.31.150
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
Aeromonas (A) gum, a stabilizer, and thickening agent of food, is composed of xylose, mannose, galactose, glucose, and mannuronic acid. Weight average molecular weights M-w and intrinsic viscosities [eta] of the unfractionated A gum and three fractions in water. 0.5 M NaCl aqueous solution and cadoxen were studied by light scattering and viscometry. Experimental results showed that A gum exists as an aggregate in 0.5 M NaCl aqueous solution and mainly as a single chain in cadoxen. The apparent aggregation number (N-sp) of A gum in 0.5 M NaCl aqueous solution was ca. 22, and decreased with increasing sample molecular weight. Change of aggregation and disaggregation of A gum in 0.5 M NaCl aqueous,cadoxen mixtures occurred from 0 to 0.4 of nu(cad) (volume fraction of cadoxen). and was reversible. The stable aggregation of A gum in 0.5 M NaCl aqueous/3% cadoxen mixture was achieved after 150 min.
引用
收藏
页码:150 / 153
页数:4
相关论文
共 50 条
[41]   Aggregation behavior of poly(N,N-diethylacrylamide) in aqueous solution [J].
Itakura, M ;
Inomata, K ;
Nose, T .
POLYMER, 2000, 41 (24) :8681-8687
[42]   State of aggregation of bilirubin in aqueous solution: principal component analysis approach [J].
Patra, SK ;
Mandal, AK ;
Pal, MK .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1999, 122 (01) :23-31
[43]   Aggregation of deuteroporphyrin IX diesters in aqueous-organic binary solution [J].
计国桢 ;
胡蕙 ;
张广明 ;
傅伟敏 ;
章道道 .
ChineseJournalofChemistry, 1998, (05) :404-413
[44]   Aggregation behavior of amphiphilic C60 derivatives in aqueous solution [J].
Pu, Zhang ;
Shuang, Lue ;
Guo Zhixin .
PROGRESS IN CHEMISTRY, 2008, 20 (04) :548-557
[45]   Aggregation Behavior of Pyridinium-Based Ionic Liquids in Aqueous Solution [J].
Isabel Bandrés ;
Sandra Meler ;
Beatriz Giner ;
Pilar Cea ;
Carlos Lafuente .
Journal of Solution Chemistry, 2009, 38 :1622-1634
[46]   Aggregation of deuteroporphyrin IX diesters in aqueous-organic binary solution [J].
Ji, GZ ;
Hu, H ;
Zhang, GM ;
Fu, WM ;
Zhang, DD .
CHINESE JOURNAL OF CHEMISTRY, 1998, 16 (05) :404-413
[47]   Electronic Absorption Spectra of Copper(Ⅱ) Sulphophthalocyanine and Aggregation of the Dye in Aqueous Solution [J].
温演庆 ;
姚永毅 ;
朱谱新 ;
吴大诚 ;
吴玉蓉 .
JournalofDonghuaUniversity(EnglishEdition), 2007, (05) :583-586
[48]   The aggregation of triphenodioxazine reactive dyes in aqueous solution and on cellulosic and nylon substrates [J].
Hihara, T ;
Okada, Y ;
Morita, Z .
DYES AND PIGMENTS, 2000, 45 (02) :131-143
[49]   Synthesis and aggregation properties of amphiphilic mono and bisadducts of fullerene in aqueous solution [J].
Zhang, Pu ;
Guo, Zhi Xin ;
Lv, Shuang .
CHINESE CHEMICAL LETTERS, 2008, 19 (09) :1039-1042
[50]   Aggregation Behavior of Pyridinium-Based Ionic Liquids in Aqueous Solution [J].
Bandres, Isabel ;
Meler, Sandra ;
Giner, Beatriz ;
Cea, Pilar ;
Lafuente, Carlos .
JOURNAL OF SOLUTION CHEMISTRY, 2009, 38 (12) :1622-1634