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Aggregation of Aeromonas gum in aqueous solution
被引:17
作者:
Zhang, L
[1
]
Xu, XJ
Jiang, GW
Iijima, H
Tsuchiya, H
机构:
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
[2] Asahi Chem Ind Co Ltd, Chem Technol Dept 4, Miyazaki 8820847, Japan
[3] Asahi Chem Ind Co Ltd, Specialty Chem Sales Dept 4, Tokyo 1008440, Japan
关键词:
aggregation;
Aeromonas gum;
light scattering;
viscometry;
polysaccharide aqueous solution;
D O I:
10.1295/polymj.31.150
中图分类号:
O63 [高分子化学(高聚物)];
学科分类号:
070305 ;
080501 ;
081704 ;
摘要:
Aeromonas (A) gum, a stabilizer, and thickening agent of food, is composed of xylose, mannose, galactose, glucose, and mannuronic acid. Weight average molecular weights M-w and intrinsic viscosities [eta] of the unfractionated A gum and three fractions in water. 0.5 M NaCl aqueous solution and cadoxen were studied by light scattering and viscometry. Experimental results showed that A gum exists as an aggregate in 0.5 M NaCl aqueous solution and mainly as a single chain in cadoxen. The apparent aggregation number (N-sp) of A gum in 0.5 M NaCl aqueous solution was ca. 22, and decreased with increasing sample molecular weight. Change of aggregation and disaggregation of A gum in 0.5 M NaCl aqueous,cadoxen mixtures occurred from 0 to 0.4 of nu(cad) (volume fraction of cadoxen). and was reversible. The stable aggregation of A gum in 0.5 M NaCl aqueous/3% cadoxen mixture was achieved after 150 min.
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页码:150 / 153
页数:4
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