α-chlorovinylation:: Synthesis of 2-chloropropenyl and propargyl alcohols

被引：15

作者：

Falck, JR ^{[1
]}

Barma, DK

Mioskowski, C

Schlama, T

机构：

[1] Univ Texas, SW Med Ctr, Dept Biochem, Dallas, TX 75235 USA

[2] Univ Texas, SW Med Ctr, Dept Pharmacol, Dallas, TX 75235 USA

[3] Univ Strasbourg 1, Fac Pharm, CNRS, Lab Synth Bioorgan, F-67401 Illkirch Graffenstaden, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 11期

关键词：

alcohols; alkenyl halides; alkynes; chromium;

D O I：

10.1016/S0040-4039(99)00153-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Formal alpha-chlorovinylation of aldehydes using CH3CCl3/CrCl2 affords 2-chloropropenyl alcohols from which terminal propargyl alcohols are obtained via base Induced elimination. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2091 / 2094

页数：4

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