Across the Board: Rui Cao on Electrocatalytic CO2 Reduction

被引：15

作者：

Cao, Rui ^{[1
]}

机构：

[1] Shaanxi Normal Univ, Sch Chem & Chem Engn, Minist Educ, Key Lab Appl Surface & Colloid Chem, Xian 710119, Peoples R China

来源：

CHEMSUSCHEM | 2022年 / 15卷 / 21期

基金：

中国国家自然科学基金;

关键词：

carbon dioxide reduction; electrocatalysis; hydrogen bonds; iron porphyrins; substituent effects;

D O I：

10.1002/cssc.202201788

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In this series of articles, the Board Members of ChemSusChem review recent research articles that they consider of exceptional quality and importance for sustainability. This entry features Prof. Rui Cao, who discusses how tuning the second-sphere environments of Fe porphyrins can improve the activity and selectivity for CO2 reduction. Substituents with proton relay capability, hydrogen-bonding, and electrostatic features have significant impact on the efficiency of Fe porphyrins for the electrocatalytic CO2 reduction reaction

引用

页数：4

共 14 条

[1] Activating the Fe(I) State of Iron Porphyrinoid with Second-Sphere Proton Transfer Residues for Selective Reduction of CO2 to HCOOH via Fe(III/II)-COOH Intermediate(s) [J].

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JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (34) :13579-13592

[2] Through-Space Charge Interaction Substituent Effects in Molecular Catalysis Leading to the Design of the Most Efficient Catalyst of CO2-to-CO Electrochemical Conversion [J].

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[3] Templating Bicarbonate in the Second Coordination Sphere Enhances Electrochemical CO2 Reduction Catalyzed by Iron Porphyrins [J].

Derrick, Jeffrey S. ;

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Chang, Christopher J. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2022, 144 (26) :11656-11663

[4]

Gotico P., 2020, ANGEW CHEM, V132, P22637

[5]

Gotico P., 2019, ANGEW CHEM, V131, P4552

[6] Atropisomeric Hydrogen Bonding Control for CO2Binding and Enhancement of Electrocatalytic Reduction at Iron Porphyrins [J].

Gotico, Philipp ;

Roupnel, Loic ;

Guillot, Regis ;

Sircoglou, Marie ;

Leibl, Winfried ;

Halime, Zakaria ;

Aukauloo, Ally .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2020, 59 (50) :22451-22455

[7] Second-Sphere Biomimetic Multipoint Hydrogen-Bonding Patterns to Boost CO2 Reduction of Iron Porphyrins [J].

Gotico, Philipp ;

Boitrel, Bernard ;

Guillot, Regis ;

Sircoglou, Marie ;

Quaranta, Annamaria ;

Halime, Zakaria ;

Leibl, Winfried ;

Aukauloo, Ally .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2019, 58 (14) :4504-4509

[8] Role-Specialized Division of Labor in CO2 Reduction with Doubly-Functionalized Iron Porphyrin Atropisomers [J].

Guo, Kai ;

Li, Xialiang ;

Lei, Haitao ;

Guo, Hongbo ;

Jin, Xiaotong ;

Zhang, Xue-Peng ;

Zhang, Wei ;

Apfel, Ulf-Peter ;

Cao, Rui .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2022, 61 (35)

[9] Through-Space Electrostatic Interactions Surpass Classical Through-Bond Electronic Effects in Enhancing CO2 Reduction Performance of Iron Porphyrins [J].

Khadhraoui, Asma ;

Gotico, Philipp ;

Leibl, Winfried ;

Halime, Zakaria ;

Aukauloo, Ally .

CHEMSUSCHEM, 2021, 14 (05) :1308-1315

[10] Oriented Electrostatic Effects on O2 and CO2 Reduction by a Polycationic Iron Porphyrin [J].

Martin, Daniel J. ;

Mayer, James M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2021, 143 (30) :11423-11434

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