High-pressure (up to 140 MPa) density and derivative properties of some (pentyl-, hexyl-, and heptyl-) amines between (293.15 and 353.15) K

被引:51
作者
Miyake, Yasufumi [1 ,2 ]
Baylaucq, Antoine [1 ]
Plantier, Frederic [1 ]
Bessieres, David [1 ]
Ushiki, Hideharu [2 ]
Boned, Christian [1 ]
机构
[1] Univ Pau & Pays Adour, UMR CNRS 5150, Fac Sci & Tech, Lab Fluides Complexes, F-64013 Pau, France
[2] Tokyo Univ Agr & Technol, Dept Environm & Nat Resource Sci, Fac Agr, Lab Mol Dynam & Complex Chem Phys, Fuchu, Tokyo 1838509, Japan
关键词
amines; density; high-pressure; isobaric thermal expansivity; isothermal compressibility;
D O I
10.1016/j.jct.2008.01.006
中图分类号
O414.1 [热力学];
学科分类号
摘要
This work reports the density data (315 points) of a series of amines consisting of pentylamine, hexylamine, and heptylamine at seven temperatures between (293.15 and 353.15) K, and pressures up to 140 MPa (every 10 MPa) which allows to study the influence of the chain length. A new Anton-Paar vibrating tube densimeter, calibrated with water and vacuum with an uncertainty of +/- 5 . 10(-4) g. cm(-3) was used to perform these measurements. The experimental density data were fitted with the Tait-like equation with low standard deviations. In addition, the isobaric thermal expansivity and the isothermal compressibility have been derived from this equation. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:836 / 845
页数:10
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