Carbon-Carbon Bond Formation via Catalytically Generated Aminocarbene Complexes: Rhodium-Catalyzed Hydroaminative Cyclization of Enynes with Secondary Amines

被引：12
|
作者：
Takano, Shotaro [1 ]
Shiomi, Ryosuke [1 ]
Morimoto, Yoshihiko [1 ]
Kochi, Takuya [1 ]
Kakiuchi, Fumitoshi [1 ]
机构：
[1] Keio Univ, Fac Sci & Technol, Dept Chem, Kohoku Ku, 3-14-1 Hiyoshi, Yokohama, Kanagawa 2238522, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 29期
关键词：
aminocarbene complexes; enynes; hydroaminative cyclization; rhodium; secondary amines; FISCHER CARBENE COMPLEXES; C-H ACTIVATION; CYCLOPROPANATION REACTIONS; INSERTION REACTIONS; CHROMIUM; CYCLOISOMERIZATION; REACTIVITY; ALKYNES; VINYLIDENE; CHEMISTRY;
D O I：
10.1002/anie.202002710
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We report a hydroaminative cyclization of enynes using phosphine-quinolinolato rhodium catalysts. The hydroaminative cyclization of 2-vinylphenylacetylene derivatives with secondary amines gives 2-aminoindenes in good yields. The reaction is considered to proceed through carbon-carbon bond formation on a catalytically generated aminocarbene ligand.
引用
收藏
页码：11754 / 11757
页数：4
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