Recent Advances in Metal-Catalyzed C-H Bond Functionalization Reactions of Sulfoxonium Ylides

被引：46
作者：
Bhorali, Pratiksha [1 ,2 ]
Sultana, Sabera [1 ]
Gogoi, Sanjib [1 ,2 ]
机构：
[1] CSIR, North East Inst Sci & Technol, Appl Organ Chem Chem Sci & Technol Div, Jorhat 785006, Assam, India
[2] Acad Sci & Innovat Res AcSIR, Ghaziabad 201002, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2022年 / 11卷 / 04期
关键词：
sulfoxonium ylide; metal-catalyzed; carbene precursor; C-H bond functionalization; heterocycles and carbocycles; INSERTION REACTIONS; RHODIUM(III)-CATALYZED ANNULATION; DIMETHYLSULFONIUM METHYLIDE; ACTIVATION; INDOLES; SALICYLALDEHYDES; ACYLMETHYLATION; CONSTRUCTION; DIMERIZATION; DERIVATIVES;
D O I：
10.1002/ajoc.202100754
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In recent years, the transition-metal-catalyzed functionalization reactions of sulfoxonium ylides have been explored extensively because of their usefulness as carbene-transfer agents, since they can produce metal carbenes through metal catalysis. Moreover, they are safer and have the advantages of simple handling and good stability over their other counterparts like diazo-compounds. This review article attempts to highlight the recent advances in the metal-catalyzed C-H functionalization of sulfoxonium ylides.
引用
收藏
页数：20
相关论文
共 110 条
[81]   Synthesis of Indoles and Pyrroles Utilizing Iridium Carbenes Generated from Sulfoxonium Ylides [J].
Vaitla, Janakiram ;
Bayer, Annette ;
Hopmann, Kathrin H. .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (15) :4277-4281
[82]   Rhodium(III)-Catalyzed Chemo-divergent Couplings of Sulfoxonium Ylides with Oxa/azabicyclic Olefins [J].
Wang, Peiyuan ;
Xu, Youwei ;
Sun, Jiaqiong ;
Li, Xingwei .
ORGANIC LETTERS, 2019, 21 (20) :8459-8463
[83]   Iridium-Catalyzed [4+2] Annulations of β-Keto Sulfoxonium Ylides ando-Phenylenediamines: Mild and Facile Synthesis of Quinoxaline Derivatives [J].
Wang, Xiao-Tong ;
Song, Jia-Lin ;
Zhong, Mei ;
Kang, Hua-Jie ;
Xie, Hui ;
Che, Tong ;
Shu, Bing ;
Peng, Dongming ;
Zhang, Luyong ;
Zhang, Shang-Shi .
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2020, 2020 (24) :3635-3639
[84]   Rhodium-catalyzed C-H activation/cyclization of enaminones with sulfoxonium ylides toward polysubstituted naphthalenes [J].
Wang, Zhenlian ;
Xu, Huang .
TETRAHEDRON LETTERS, 2019, 60 (09) :664-667
[85]   Ruthenium(II)-Catalyzed Construction of Isocoumarins via Dual C-H/C-C Activation of Sulfoxonium Ylides [J].
Wen, Si ;
Chen, Yanhui ;
Zhao, Zemin ;
Ba, Dan ;
Lv, Weiwei ;
Cheng, Guolin .
JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (02) :1216-1223
[86]   Ruthenium(ii)-catalyzed chemoselective deacylative annulation of 1,3-diones with sulfoxonium ylides via C-C bond activation [J].
Wen, Si ;
Lv, Weiwei ;
Ba, Dan ;
Liu, Jing ;
Cheng, Guolin .
CHEMICAL SCIENCE, 2019, 10 (39) :9104-9108
[87]   Ruthenium(ii)-catalyzed selective C-H bond activation of imidamides and coupling with sulfoxonium ylides: an efficient approach for the synthesis of highly functional 3-ketoindoles [J].
Wu, Chenglin ;
Zhou, Jianhui ;
He, Guoxue ;
Li, Huihui ;
Yang, Qiaolan ;
Wang, Run ;
Zhou, Yu ;
Liu, Hong .
ORGANIC CHEMISTRY FRONTIERS, 2019, 6 (08) :1183-1188
[88]   Rhodium-Catalyzed Reaction of Sulfoxonium Ylides and Anthranils toward Indoloindolones via a (4+1) Annulation [J].
Wu, Xiaopeng ;
Xiao, Yan ;
Sun, Song ;
Yu, Jin-Tao ;
Cheng, Jiang .
ORGANIC LETTERS, 2019, 21 (17) :6653-6657
[89]   Recent Applications of -Carbonyl Sulfoxonium Ylides in Rhodium- and Iridium-Catalyzed C-H Functionalizations [J].
Wu, Xiaopeng ;
Sun, Song ;
Yu, Jin-Tao ;
Cheng, Jiang .
SYNLETT, 2019, 30 (01) :21-29
[90]   Rh(III)-Catalyzed Tandem Acylmethylation/Nitroso Migration/Cyclization of N-Nitrosoanilines with Sulfoxonium Ylides in One Pot: Approach to 3-Nitrosoindoles [J].
Wu, Yingtao ;
Pi, Chao ;
Cui, Xiuling ;
Wu, Yangjie .
ORGANIC LETTERS, 2020, 22 (02) :361-364
234567891011