Ruthenium(II) complexes of Chelating Ligands containing benzoxazole and benzothiazole subunits: Synthesis, X-ray crystallography, spectroscopy, and Electrochemistry

被引:10
|
作者
Richardson, Chris [1 ]
Keene, F. Richard [2 ]
Steel, Peter J. [1 ]
机构
[1] Univ Canterbury, Coll Sci, Dept Chem, Christchurch 8140, New Zealand
[2] James Cook Univ N Queensland, Sch Pharm & Mol Sci, Townsville, Qld 4811, Australia
基金
澳大利亚研究理事会;
关键词
D O I
10.1071/CH08021
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Bis( 2,2'- bipyridyl) ruthenium(II) complexes of four chelating ligands that contain benzoxazole or benzothiazole rings have been prepared and characterized by NMR spectroscopy, visible absorption spectroscopy, electrochemical measurements and, in two cases, by X- ray crystallography. The incorporation of these ring systems has a marked effect on the electronic properties of the resulting complexes.
引用
收藏
页码:183 / 188
页数:6
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