Conjugated Copolymers of Vinylene Flanked Naphthalene Diimide

被引：49
作者：
Fei, Zhuping [1 ,2 ]
Han, Yang [1 ,2 ,3 ]
Martin, Jaime [2 ,4 ]
Scholes, Fiona H. [5 ]
Al-Hashimi, Mohammed [7 ]
AlQaradawi, Siham Y. [6 ]
Stingelin, Natalie [2 ,4 ]
Anthopoulos, Thomas D. [2 ,3 ]
Heeney, Martin [1 ,2 ]
机构：
[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England
[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England
[3] Imperial Coll London, Dept Phys, London SW7 2AZ, England
[4] Imperial Coll London, Dept Mat, London SW7 2AZ, England
[5] CSIRO Mfg, Private Bag 10, Clayton, Vic 3169, Australia
[6] Qatar Univ, Dept Chem & Earth Sci, POB 2713, Doha, Qatar
[7] Texas A&M Univ Qatar, Dept Chem, POB 23874, Doha, Qatar
来源：
MACROMOLECULES | 2016年 / 49卷 / 17期
关键词：
FIELD-EFFECT TRANSISTORS; CHANNEL ORGANIC TRANSISTORS; HIGH-ELECTRON-MOBILITY; POLYMER SOLAR-CELLS; N-CHANNEL; CHARGE-TRANSPORT; SEMICONDUCTING POLYMERS; HIGH-PERFORMANCE; DIRECT ARYLATION; HIGH HOLE;
D O I：
10.1021/acs.macromol.6b01423
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the synthesis of a novel naphthalene diimide (NDI) monomer containing two (tributylstannyl)vinyl groups. The utility of this building block is demonstrated by its copolymerization with five different electron-rich comonomers under Stille conditions. The resulting high molecular weight polymers show red-shifted optical absorptions in comparison to the analogous polymers without the vinylene spacer and a significant increase in the intensity of the low-energy intramolecular charge transfer band. The polymers all exhibit ambipolar behavior in bottom-gate, top-contact organic thin-film transistors. The insertion of a solution-processed barium hydroxide layer between the polymer and the gold electrode led to unipolar behavior with improved electron mobilities.
引用
收藏
页码：6384 / 6393
页数：10
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