Conjugated Copolymers of Vinylene Flanked Naphthalene Diimide

被引：49
作者：
Fei, Zhuping [1 ,2 ]
Han, Yang [1 ,2 ,3 ]
Martin, Jaime [2 ,4 ]
Scholes, Fiona H. [5 ]
Al-Hashimi, Mohammed [7 ]
AlQaradawi, Siham Y. [6 ]
Stingelin, Natalie [2 ,4 ]
Anthopoulos, Thomas D. [2 ,3 ]
Heeney, Martin [1 ,2 ]
机构：
[1] Imperial Coll London, Dept Chem, London SW7 2AZ, England
[2] Imperial Coll London, Ctr Plast Elect, London SW7 2AZ, England
[3] Imperial Coll London, Dept Phys, London SW7 2AZ, England
[4] Imperial Coll London, Dept Mat, London SW7 2AZ, England
[5] CSIRO Mfg, Private Bag 10, Clayton, Vic 3169, Australia
[6] Qatar Univ, Dept Chem & Earth Sci, POB 2713, Doha, Qatar
[7] Texas A&M Univ Qatar, Dept Chem, POB 23874, Doha, Qatar
来源：
MACROMOLECULES | 2016年 / 49卷 / 17期
关键词：
FIELD-EFFECT TRANSISTORS; CHANNEL ORGANIC TRANSISTORS; HIGH-ELECTRON-MOBILITY; POLYMER SOLAR-CELLS; N-CHANNEL; CHARGE-TRANSPORT; SEMICONDUCTING POLYMERS; HIGH-PERFORMANCE; DIRECT ARYLATION; HIGH HOLE;
D O I：
10.1021/acs.macromol.6b01423
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
We report the synthesis of a novel naphthalene diimide (NDI) monomer containing two (tributylstannyl)vinyl groups. The utility of this building block is demonstrated by its copolymerization with five different electron-rich comonomers under Stille conditions. The resulting high molecular weight polymers show red-shifted optical absorptions in comparison to the analogous polymers without the vinylene spacer and a significant increase in the intensity of the low-energy intramolecular charge transfer band. The polymers all exhibit ambipolar behavior in bottom-gate, top-contact organic thin-film transistors. The insertion of a solution-processed barium hydroxide layer between the polymer and the gold electrode led to unipolar behavior with improved electron mobilities.
引用
收藏
页码：6384 / 6393
页数：10
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  • [1] n-Type Organic Semiconductors in Organic Electronics
    Anthony, John E.
    Facchetti, Antonio
    Heeney, Martin
    Marder, Seth R.
    Zhan, Xiaowei
    [J]. ADVANCED MATERIALS, 2010, 22 (34) : 3876 - 3892
  • [2] Ambipolar organic field-effect transistors based on a solution-processed methanofullerene
    Anthopoulos, TD
    Tanase, C
    Setayesh, S
    Meijer, EJ
    Hummelen, JC
    Blom, PWM
    de Leeuw, DM
    [J]. ADVANCED MATERIALS, 2004, 16 (23-24) : 2174 - +
  • [3] Air-stable ambipolar organic transistors
    Anthopoulos, Thomas D.
    Anyfantis, G. C.
    Papavassiliou, G. C.
    de Leeuw, Dago M.
    [J]. APPLIED PHYSICS LETTERS, 2007, 90 (12)
  • [4] Air-stable complementary-like circuits based on organic ambipolar transistors
    Anthopoulos, Thomas D.
    Setayesh, Sepas
    Smits, Edsger
    Colle, Michael
    Cantatore, Eugenio
    de Boer, Bert
    Blom, Paul W. M.
    de Leeuw, Dago M.
    [J]. ADVANCED MATERIALS, 2006, 18 (14) : 1900 - +
  • [5] Materials and Applications for Large Area Electronics: Solution-Based Approaches
    Arias, Ana Claudia
    MacKenzie, J. Devin
    McCulloch, Iain
    Rivnay, Jonathan
    Salleo, Alberto
    [J]. CHEMICAL REVIEWS, 2010, 110 (01) : 3 - 24
  • [6] High electron mobility in ladder polymer field-effect transistors
    Babel, A
    Jenekhe, SA
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (45) : 13656 - 13657
  • [7] Naphthalenediimide-Based Copolymers Incorporating Vinyl-Linkages for High-Performance Ambipolar Field-Effect Transistors and Complementary-Like Inverters under Air
    Chen, Huajie
    Guo, Yunlong
    Mao, Zupan
    Yu, Gui
    Huang, Jianyao
    Zhao, Yan
    Liu, Yunqi
    [J]. CHEMISTRY OF MATERIALS, 2013, 25 (18) : 3589 - 3596
  • [8] Naphthalenedicarboximide- vs Perylenedicarboximide-Based Copolymers. Synthesis and Semiconducting Properties in Bottom-Gate N-Channel Organic Transistors
    Chen, Zhihua
    Zheng, Yan
    Yan, He
    Facchetti, Antonio
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (01) : 8 - +
  • [9] High-Performance Ambipolar Diketopyrrolopyrrole-Thieno[3,2-b]thiophene Copolymer Field-Effect Transistors with Balanced Hole and Electron Mobilities
    Chen, Zhuoying
    Lee, Mi Jung
    Ashraf, Raja Shahid
    Gu, Yun
    Albert-Seifried, Sebastian
    Nielsen, Martin Meedom
    Schroeder, Bob
    Anthopoulos, Thomas D.
    Heeney, Martin
    McCulloch, Iain
    Sirringhaus, Henning
    [J]. ADVANCED MATERIALS, 2012, 24 (05) : 647 - +
  • [10] Synthesis and Characterization of Thiophene-Containing Naphthalene Diimide n-Type Copolymers for OFET Applications
    Durban, Matthew M.
    Kazarinoff, Peter D.
    Luscombe, Christine K.
    [J]. MACROMOLECULES, 2010, 43 (15) : 6348 - 6352
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