Phase-field analysis of a ternary two-phase diffusion couple with multiple analytical solutions

被引:12
作者
Heulens, J. [1 ]
Blanpain, B. [1 ]
Moelans, N. [1 ]
机构
[1] Katholieke Univ Leuven, Dept Met & Mat Engn, B-3001 Heverlee, Belgium
关键词
Phase-field models; Diffusion; Theory and modeling; Computational thermodynamics; Diffusion couple; TRANSFORMATIONS; SIMILARITY; PRINCIPLE; DATABASE; PATHS;
D O I
10.1016/j.actamat.2011.03.020
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Under certain conditions, there are multiple analytical solutions for the interface velocity in ternary two-phase diffusion couples. We have tackled this degeneracy problem by employing an isothermal phase-field model for diffusion couples that allows comparison with the analytical solutions. We find that, besides the three analytically predicted single-interface diffusion paths, a triple-interface diffusion path can also form. Furthermore, analysis of the phase-field simulation results shows that the Gibbs energies of both the bulk phases and the interfaces must be considered to determine uniquely the evolution of a diffusion couple, in case whether a single or multiple interfaces form. (C) 2011 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:3946 / 3954
页数:9
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