Solubility of pyrene in ternary propanol plus butanol plus cyclohexane solvent mixtures at 299.15 K

被引:14
作者
Debase, EM [1 ]
Acree, WE [1 ]
机构
[1] Univ N Texas, Dept Chem, Denton, TX 76203 USA
关键词
D O I
10.1021/je010112l
中图分类号
O414.1 [热力学];
学科分类号
摘要
Experimental solubilities are reported for pyrene dissolved in ternary l-propanol + l-butanol + cyclohexane, 2-propanol + l-butanol + cyclohexane, l-propanol + a-butanol + cyclohexane, and 2-propanol + 2-butanol + cyclohexane solvent mixtures at 26 degreesC and atmospheric pressure. Nineteen compositions were studied for each of the four solvent systems. Results of these measurements are used to test the predictive ability of the ternary solvent foam of the combined NIMS/Redlich-Kister equation. Computations showed that the model predicted the observed solubility behavior to within an overall average absolute deviation of about 1.2%, which is comparable to the experimental uncertainty of +/-1.5%.
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页码:991 / 993
页数:3
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