Preparation-and Spectroscopic Characterization of Transition Metal Complexes with Schiff base 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol

被引:6
作者
Al-Daffaay, Rasha KhiderHussain [1 ]
机构
[1] Univ Baghdad, Coll Sci, Dept Chem, Baghdad, Iraq
关键词
Mass spectra; Metal Complexes; Schiff base; LIGAND SYNTHESIS;
D O I
10.21123/bsj.2022.6162
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
The ligand 2-[1-(1H-indol-3-yl)ethylimino) methyl]naphthalene-1-ol, derived from 1-hydroxy-2naphthaldehyde and 2-(1H-indol-3-yl)ethylamine, was used to produce a new sequence of metal ions complexes. Thus ligand reactions with NiCl2.6H2O, PdCl2, FeCl3.6H2O and H2PtCl6.6H2O were sequentially visible), Mass Spectra analysis, Bohr-magnetic (B.M.), metal content, chloride content and molar conductivity have been the defining features of the composites. The Fe(III) and Pt(IV) complexes have octahedral geometries, while the Ni(II) complex has tetrahedral geometry and the Pd (II) complex has square planer geometry, according to these findings.
引用
收藏
页码:1036 / 1044
页数:9
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