NMR study of the stoichiometry and stability of complexation reaction between Mg2+, Ca2+, Sr2+ and Ba2+ ions and 60-crown-20 in binary acetonitrile solvent mixtures

被引：4
|
作者：
Rahimi-Nasrabadi, M. [1 ]
Pourmohamadian, S. [2 ]
Pourmortazavi, S. M. [3 ]
Ahmadi, F. [4 ]
Ganjali, M. R. [5 ]
Moghimi, A. [1 ]
机构：
[1] Imam Hossein Univ, Dept Chem, Tehran, Iran
[2] Islamic Azad Univ, Varamin Pishva Branch, Varamin, Iran
[3] Malek Ashtar Univ Technol, Fac Mat & Mfg Technol, Tehran, Iran
[4] Kermanshah Univ Med Sci, Fac Pharm, Dept Med Chem, Kermanshah, Iran
[5] Univ Tehran, Fac Chem, Tehran, Iran
来源：
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY | 2012年 / 73卷 / 1-4期
关键词：
60-Crown-20; NMR; Mixed solvents; Complex formation constants; METAL-IONS; MACROCYCLE INTERACTION; KINETIC-DATA; POTASSIUM; TRANSPORT; SODIUM; LIGAND;
D O I：
10.1007/s10847-011-0051-2
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Proton nuclear magnetic resonance (H-1-NMR) spectroscopy was used to study the complexation reaction between Mg2+, Ca2+, Sr2+ and Ba2+ ions and 60-crown-20 in a series of binary mixtures of deuterated acetonitrile (AN), nitromethane (NM) and D2O at 27 A degrees C. Formation constants of the 1:1 complexes were determined through computer fitting of the chemical shift/mol ratio data and found to vary in the order of Ba2+ > Sr2+ > Mg2+ a parts per thousand Ca2+. The influence of the solvent composition on the stability of the resulting complexes was also discussed. In all cases, the changes in the stability constants with the solvent composition were monotonic and showed a good correlation with the inherent solvation ability of the pure solvents which form the mixture.
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页码：263 / 267
页数：5
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