From six-coordinate to eight-coordinate iron(II) complexes with pyridyltriazolo-pyridine frameworks

被引：10
|
作者：
Adam, Rosa [1 ]
Ballesteros-Garrido, Rafael [1 ]
Ferrer, Sacramento [2 ]
Abarca, Belen [1 ]
Ballesteros, Rafael [1 ]
Antonio Real, Jose [3 ]
Carmen Munoz, M. [4 ]
机构：
[1] Univ Valencia, Dept Quim Organ, Av Vicent Andres Estelles S-N, E-46100 Valencia, Spain
[2] Univ Valencia, Dept Quim Inorgan, Av Vicent Andres Estelles S-N, E-46100 Valencia, Spain
[3] Univ Valencia, Inst Ciencia Mol ICMol, C Catedrat Jose Beltran 2, Valencia 46980, Spain
[4] Univ Politecn Valencia, Dept Fis Aplicada, C Camino Vera S-N, E-46022 Valencia, Spain
来源：
CRYSTENGCOMM | 2016年 / 18卷 / 41期
关键词：
SPIN-CROSSOVER; CRYSTAL-STRUCTURE; LIGAND; TRIAZOLOPYRIDINES; TRANSITIONS; ROUTE; IONS;
D O I：
10.1039/c6ce01540a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new octacoordinated Fe(II) compound, [(FeLN4)-L-II()(2)](BPh4)(2)center dot 3CH(2)Cl(2), as an example of the scarce FeN8 systems, has been isolated with a tetradentate triazolopyridine-based ligand from a solution containing the related hexacoordinated [FeII(LN3)(2)](2+) complex, with L-N3 = pyridyltriazolo-pyridyl-bromopyrimidine and L-N4 = bis(pyridyltriazolo-pyridine).
引用
收藏
页码：7950 / 7954
页数：5
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