From six-coordinate to eight-coordinate iron(II) complexes with pyridyltriazolo-pyridine frameworks

被引：10

作者：

Adam, Rosa ^{[1
]}

Ballesteros-Garrido, Rafael ^{[1
]}

Ferrer, Sacramento ^{[2
]}

Abarca, Belen ^{[1
]}

Ballesteros, Rafael ^{[1
]}

Antonio Real, Jose ^{[3
]}

Carmen Munoz, M. ^{[4
]}

机构：

[1] Univ Valencia, Dept Quim Organ, Av Vicent Andres Estelles S-N, E-46100 Valencia, Spain

[2] Univ Valencia, Dept Quim Inorgan, Av Vicent Andres Estelles S-N, E-46100 Valencia, Spain

[3] Univ Valencia, Inst Ciencia Mol ICMol, C Catedrat Jose Beltran 2, Valencia 46980, Spain

[4] Univ Politecn Valencia, Dept Fis Aplicada, C Camino Vera S-N, E-46022 Valencia, Spain

来源：

CRYSTENGCOMM | 2016年 / 18卷 / 41期

关键词：

SPIN-CROSSOVER; CRYSTAL-STRUCTURE; LIGAND; TRIAZOLOPYRIDINES; TRANSITIONS; ROUTE; IONS;

D O I：

10.1039/c6ce01540a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new octacoordinated Fe(II) compound, [(FeLN4)-L-II()(2)](BPh4)(2)center dot 3CH(2)Cl(2), as an example of the scarce FeN8 systems, has been isolated with a tetradentate triazolopyridine-based ligand from a solution containing the related hexacoordinated [FeII(LN3)(2)](2+) complex, with L-N3 = pyridyltriazolo-pyridyl-bromopyrimidine and L-N4 = bis(pyridyltriazolo-pyridine).

引用

页码：7950 / 7954

页数：5

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