Influence of process parameters on property of PP/EPDM blends prepared by a novel vane extruder

被引:10
作者
Zou, Wei [1 ]
Chen, Rong-yuan [1 ]
Wu, Chengran [1 ]
Qu, Jin-ping [1 ]
机构
[1] South China Univ Technol, Minist Educ, Key Lab Polymer Proc Engn, Natl Engn Res Ctr Novel Equipment Polymer Proc, Guangzhou 510640, Guangdong, Peoples R China
基金
新加坡国家研究基金会; 中国国家自然科学基金;
关键词
ethylene-propylene-diene terpolymer; poly-propylene; vane extruder; MECHANICAL-PROPERTIES; EPDM/PP BLEND; MORPHOLOGY; POLYMER; RHEOLOGY; MICROSTRUCTURE; POLYPROPYLENE; DISPERSION; VISCOSITY; PHASE;
D O I
10.1515/polyeng-2015-0386
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this study, thermoplastic elastomers based on polypropylene (PP) and ethylene-propylene-diene terpolymer (EPDM) were prepared via direct melt blending in a novel vane extruder. The influence of processing-temperature and rotor speed on the degree of cross-linking of the EPDM phase, the tensile properties, the melting behavior and the crystallization morphology of PP/EPDM blends was investigated. It was observed that the volume fraction (V-r) of the vulcanizate arriving swelling equilibrium reached the maximum value when the processing temperature was 190 degrees C. The tensile properties showed better-performance at 195 degrees C, at which the PP/EPDM blend obtained good dispersive mixing performance. Moreover, the V-r of the vulcanizate arriving swelling equilibrium reached the maximum value when the rotor speed was 60 rpm, at which the dispersive mixing performance and tensile properties of the PP/EPDM blend were better.
引用
收藏
页码:899 / 908
页数:10
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