High-temperature pyrolysis behavior of a bituminous coal in a drop tube furnace and further characterization of the resultant char

In order to study the high-temperature pyrolysis behavior of bituminous coal in the drop tube furnace (DTF) and better utilization of the obtained char, a typical Shenhua bituminous coal (SH) was pyrolyzed in a DTF at the temperatures of 1000-1300 degrees C (100 degrees C increments). The obtained char was then characterized using BET and FTIR methods, while its combustion, gasification and pollutant emission characteristics were explored by a thermogravimetric analyzer and online flue gas analyzer. Results show that higher pyrolysis temperature leads to more CO and less CH4 for the increased free radical rearrangement by high heating rate and carbon reduction reactions at high temperatures. Pyrolysis generally decomposes the functional groups, increases the volume of char pores, and upgrades the rank of coal. The combustion activation energy increases from 22.99 kJ/mol to 27.42 kJ/mol and the gasification is hindered with the higher pyrolysis temperature. It is notable that the NOx and SO2 emissions of the obtained char combustion are both below 30 mg/s-MJ. High-temperature pyrolysis can enhance the evolution of NH3 and HCN as volatiles, thus decreasing the NOx formation in further char combustion stages while partly decomposing the organic and inorganic sulfur compounds to impact the SO2 emission.