Strategies and challenges on selective electrochemical hydrogen peroxide production: Catalyst and reaction medium design

被引:70
作者
Dan, Meng [1 ,2 ,3 ]
Zhong, Ruyi [1 ]
Hu, Shangyu [1 ]
Wu, Huixiang [1 ]
Zhou, Ying [2 ]
Liu, Zhao-Qing [1 ]
机构
[1] Guangzhou Univ, Sch Chem & Chem Engn, Guangzhou Key Lab Clean Energy & Mat, Minist Educ,Key Lab Water Qual & Conservat Pearl, Guangzhou 510006, Peoples R China
[2] Southwest Petr Univ, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610500, Peoples R China
[3] Nanchang Hangkong Univ, Natl Local Joint Engn Res Ctr Heavy Met Pollutant, Nanchang 330063, Jiangxi, Peoples R China
来源
CHEM CATALYSIS | 2022年 / 2卷 / 08期
基金
中国博士后科学基金; 中国国家自然科学基金;
关键词
OXYGEN REDUCTION REACTION; NITROGEN-DOPED CARBON; DIRECT H2O2 PRODUCTION; FUEL-CELL CATALYST; O-2; REDUCTION; ELECTROCATALYTIC SYNTHESIS; UNDERPOTENTIAL DEPOSITION; DISPERSED PLATINUM; ELECTRON-TRANSFER; ACTIVE-SITES;
D O I
10.1016/j.checat.2022.06.002
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen peroxide (H2O2), as a valuable fuel and oxidant, has attracted increasing attention in the energy and environmentalrelated areas. The electrochemical oxygen reduction reaction (ORR) with a prominent 2-electron (2e(-)) pathway has been recognized as a ``green'' route for the direct synthesis of H2O2 and its on-site utilization. A systematic summary on rational design of catalyst systems (i.e., the catalyst and the reaction medium) for selective electrochemical H2O2 production is still lacking, which is critical for advancing this burgeoning field. Here, fundamental knowledge of electrochemical H2O2- related reactions including the reaction mechanism and the performance (activity, selectivity, and stability) descriptors is introduced in the beginning of this review. Afterward, the cutting-edge electrocatalyst and reaction medium (i.e., electrolyte) design strategies for H2O2 generation via 2e(-) ORR pathway are reviewed, with a special emphasis on selectivity regulation. Finally, critical perspectives are presented on the challenges and opportunities on the selective electrochemical H2O2 production.
引用
收藏
页码:1919 / 1960
页数:42
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