Synthesis of controlled structure water-soluble diblock copolymers via oxyanionic polymerization

被引：133
作者：
Vamvakaki, M [1 ]
Billingham, NC [1 ]
Armes, SP [1 ]
机构：
[1] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England
来源：
MACROMOLECULES | 1999年 / 32卷 / 06期
关键词：
D O I：
10.1021/ma981779o
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Monohydroxy-capped poly(alkylene oxide)s were used as macroinitiators for the polymerization of several tertiary amine methacrylates namely, DMAEMA, DEAEMA, 2-(N-morpholino) ethyl methacrylate (MEMA), and 2-(diisopropylamino) ethyl methacrylate (DPAEMA). High yields and good control over copolymer molecular weight were obtained for the polymerization of all four tertiary amine methacrylate monomers.
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页码：2088 / 2090
页数：3
相关论文
共 33 条
[1]   Neutron reflectivity of an adsorbed water-soluble block copolymer: A surface transition to micelle-like aggregates at the air/water interface [J].
An, SW ;
Su, TJ ;
Thomas, RK ;
Baines, FL ;
Billingham, NC ;
Armes, SP ;
Penfold, J .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (02) :387-393
[2]   Use of block copolymer stabilizers for the dispersion polymerization of styrene in alcoholic media [J].
Baines, FL ;
Dionisio, S ;
Billingham, NC ;
Armes, SP .
MACROMOLECULES, 1996, 29 (09) :3096-3102
[3]   Synthesis and solution properties of water-soluble hydrophilic-hydrophobic block copolymers [J].
Baines, FL ;
Billingham, NC ;
Armes, SP .
MACROMOLECULES, 1996, 29 (10) :3416-3420
[4]   Micellization of poly(2-(dimethylamino)ethyl methacrylate-block-methyl methacrylate) copolymers in aqueous solution [J].
Baines, FL ;
Armes, SP ;
Billingham, NC ;
Tuzar, Z .
MACROMOLECULES, 1996, 29 (25) :8151-8159
[5]   Novel family of thermogelling materials via C-C bonding between poly(acrylic acid) and poly(ethylene oxide)-b-poly(propylene oxide)-b-poly(ethylene oxide) [J].
Bromberg, L .
JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (11) :1956-1963
[6]   Synthesis of shell cross-linked micelles with tunable hydrophilic/hydrophobic cores [J].
Bütün, V ;
Billingham, NC ;
Armes, SP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (46) :12135-12136
[7]   Unusual aggregation behavior of a novel tertiary amine methacrylate-based diblock copolymer: Formation of micelles and reverse micelles in aqueous solution [J].
Butun, V ;
Billingham, NC ;
Armes, SP .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (45) :11818-11819
[8]   Selective betainisation of tertiary amine methacrylate block copolymers [J].
Butun, V ;
Bennett, CE ;
Vamvakaki, M ;
Lowe, AB ;
Billingham, NC ;
Armes, SP .
JOURNAL OF MATERIALS CHEMISTRY, 1997, 7 (09) :1693-1695
[9]  
BUTUN V, 1997, CHEM COMMUN, P697
[10]  
BUTUN V, UNPUB
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