Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements

被引：163

作者：

Bauza, Antonio ^{[1
]}

Alkorta, Ibon ^{[2
]}

Elguero, Jose ^{[2
]}

Mooibroek, Tiddo J. ^{[3
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

[2] Inst Quim Med, Juan Cierva 3, Madrid 28006, Spain

[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, Sci Pk A 904,E1-26, NL-1098 XH Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 40期

关键词：

ab initio calculations; donor-acceptor systems; non-covalent bonding; spodium bonds; supramolecular chemistry; DER-WAALS RADII; VAN;

D O I：

10.1002/anie.202007814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.

引用

页码：17482 / 17487

页数：6

共 33 条

[1] Not Only Hydrogen Bonds: Other Noncovalent Interactions
Alkorta, Ibon
Elguero, Jose
Frontera, Antonio
[J]. CRYSTALS, 2020, 10 (03)
[2] Aspinall H.C., 2018, Chemistry of the F-Block Elements
[3] Van der Waals radii of elements
Batsanov, SS
[J]. INORGANIC MATERIALS, 2001, 37 (09) : 871 - 885
[4] σ/π-Hole noble gas bonding interactions: Insights from theory and experiment
Bauza, Antonio
Frontera, Antonio
[J]. COORDINATION CHEMISTRY REVIEWS, 2020, 404
[5] The Bright Future of Unconventional σ/-Hole Interactions
Bauza, Antonio
Mooibroek, Tiddo J.
Frontera, Antonio
[J]. CHEMPHYSCHEM, 2015, 16 (12) : 2496 - 2517
[6] Anion Transport with Chalcogen Bonds
Benz, Sebastian
Macchione, Mariano
Verolet, Quentin
Mareda, Jiri
Sakai, Naomi
Matile, Stefan
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2016, 138 (29) : 9093 - 9096
[7] Chalcogen-bond driven molecular recognition at work
Biot, Nicolas
Bonifazi, Davide
[J]. COORDINATION CHEMISTRY REVIEWS, 2020, 413
[8] VAN DER WAALS VOLUMES + RADII
BONDI, A
[J]. JOURNAL OF PHYSICAL CHEMISTRY, 1964, 68 (03) : 441 - +
[9] THE VANDERWAALS RADIUS OF MERCURY
CANTY, AJ
DEACON, GB
[J]. INORGANICA CHIMICA ACTA-LETTERS, 1980, 45 (06): : L225 - L227
[10] Naming Interactions from the Electrophilic Site
Cavallo, Gabriella
Metrangolo, Pierangelo
Pilati, Tullio
Resnati, Giuseppe
Terraneo, Giancarlo
[J]. CRYSTAL GROWTH & DESIGN, 2014, 14 (06) : 2697 - 2702

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