Spodium Bonds: Noncovalent Interactions Involving Group 12 Elements

被引：179

作者：

Bauza, Antonio ^{[1
]}

Alkorta, Ibon ^{[2
]}

Elguero, Jose ^{[2
]}

Mooibroek, Tiddo J. ^{[3
]}

Frontera, Antonio ^{[1
]}

机构：

[1] Univ Illes Balears, Dept Quim, Crta Valldemossa Km 7-5, Palma De Mallorca 07122, Baleares, Spain

[2] Inst Quim Med, Juan Cierva 3, Madrid 28006, Spain

[3] Univ Amsterdam, Vant Hoff Inst Mol Sci, Sci Pk A 904,E1-26, NL-1098 XH Amsterdam, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2020年 / 59卷 / 40期

关键词：

ab initio calculations; donor-acceptor systems; non-covalent bonding; spodium bonds; supramolecular chemistry; DER-WAALS RADII; VAN;

D O I：

10.1002/anie.202007814

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The term spodium (Sp) bond is proposed to refer to a net attractive interaction between any element of Group 12 and electron-rich atoms (Lewis bases or anions). These noncovalent interactions are markedly different from coordination bonds (antibonding Sp-ligand orbital involved). Evidence is provided for the existence of this interaction by calculations at the RI-MP2/aug-cc-pVTZ level of theory, atoms-in-molecules, and natural bond orbital analyses and by examining solid-state structures in the Cambridge Structure Database.

引用

页码：17482 / 17487

页数：6

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