DME as reductant for continuous lean reduction of NOx over ZSM-5 catalysts

被引:8
|
作者
Tamm, Stefanie [1 ]
Ingelsten, Hanna H. [1 ]
Palmqvist, Anders E. C. [1 ]
机构
[1] Chalmers, Competence Ctr Catalysis, Dept Chem & Biol Engn, S-41296 Gothenburg, Sweden
关键词
dimethyl ether; DME; NO(x) reduction; ZSM-5; NO(2); solid acid; zeolite;
D O I
10.1007/s10562-008-9487-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Dimethyl ether (DME) is an interesting alternative fuel to diesel, but is not an efficient reductant in lean NO (x) conversion over typical diesel HC-SCR catalysts. Comparatively high deNO(x) activity was found over H-ZSM-5 in the presence of water, giving reduction of 28% NO and 37% NO(2) respectively with a DME/NO(x)-ratio of 4.
引用
收藏
页码:233 / 238
页数:6
相关论文
共 50 条
  • [41] A combined system of dimethyl ether (DME) steam reforming and lean NOx trap catalysts to improve NOx reduction in DME engines
    Park, Syungyong
    Choi, Byungchul
    Oh, Byeong-Soo
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2011, 36 (11) : 6422 - 6432
  • [42] On the selectively catalytic reduction of NOx with methane over Ag-ZSM-5 catalysts
    Shi, C
    Cheng, MJ
    Qu, ZP
    Yang, XF
    Bao, XH
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2002, 36 (03) : 173 - 182
  • [43] Artificial intelligence modeling of DME conversion to gasoline and light olefins over modified nano ZSM-5 catalysts
    Hajjar, Zeinab
    Khodadadi, Abbasali
    Mortazavi, Yadollah
    Tayyebi, Shokoufe
    Soltanali, Saeed
    FUEL, 2016, 179 : 79 - 86
  • [44] Synthesis of pyridines over modified ZSM-5 catalysts
    Slobodník, M
    Hronec, M
    Cvengrosová, Z
    Kaszonyi, A
    MOLECULAR SIEVES: FROM BASIC RESEARCH TO INDUSTRIAL APPLICATIONS, PTS A AND B, 2005, 158 : 1835 - 1842
  • [45] NOx reduction by CO over Fe/ZSM-5: A comparative study of different preparation techniques
    Li, Jianjie
    Zhao, Mingliang
    Zhang, Ming
    Cheng, Xingxing
    Chang, Jingcai
    Wang, Zhiqiang
    Fu, Jiapeng
    Sun, Yiqing
    Liu, Xiuru
    INTERNATIONAL JOURNAL OF CHEMICAL REACTOR ENGINEERING, 2020, 18 (02)
  • [46] Decomposition of nitrous oxide over ZSM-5 catalysts
    Kapteijn, F
    Mul, G
    Marban, G
    RodriguezMirasol, J
    Moulijn, JA
    11TH INTERNATIONAL CONGRESS ON CATALYSIS - 40TH ANNIVERSARY, PTS A AND B, 1996, 101 : 641 - 650
  • [47] Decoupled NOx adsorption and reduction by CO over catalyst Fe/ZSM-5: A DFT study
    Sun, Peiliang
    Fan, Kai
    Cheng, Xingxing
    Qian, Zhao
    Wang, Zhiqiang
    Wang, Luyuan
    Jen, Tien-Chien
    CHEMICAL PHYSICS LETTERS, 2021, 766
  • [48] Methylation of toluene with methane over ZSM-5 catalysts
    Adebajo, MO
    Howe, RF
    Long, MA
    ENERGY & FUELS, 2001, 15 (03) : 671 - 674
  • [49] Selective Catalytic Reduction of NO in Excess Oxygen by Methane over Mn/ZSM-5 Catalysts
    Chen Shuwei
    Yan Xiaoliang
    Chen Jiaqi
    Ma Jinghong
    Li Ruifeng
    CHINESE JOURNAL OF CATALYSIS, 2010, 31 (09) : 1107 - 1114
  • [50] On the nature of active sites in Fe/ZSM-5 catalysts for NOx abatement
    Voskoboinikov, TV
    Chen, HY
    Sachtler, WMH
    APPLIED CATALYSIS B-ENVIRONMENTAL, 1998, 19 (3-4) : 279 - 287