Collision-induced absorption in the second overtone band of H2

被引:3
|
作者
Abu-Kharma, M. [1 ]
机构
[1] Al Balqa Appl Univ, Dept Appl Sci, Amman 11134, Jordan
关键词
HYDROGEN; SPECTRA; Q(1)(J(1))+Q(1)(J(2))+Q(1)(J(3)); ATMOSPHERES; PAIRS;
D O I
10.1139/P2012-022
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The second overtone band of H-2-H-2 spectra at 77 K were recorded for gas densities between 350 and 1000 amg (1 amg = 44.614 981 mol/m(3)) with a 2 m stainless steel high-pressure transmission-type absorption cell. The profile analyses of these spectra were carried out using the Birnbaum-Cohen line shape function for the quadrupolar transitions and the Levine-Birnbaum line shape function for the overlap transitions. The observed spectra were modeled with synthetic profiles which are composed of the superposition of an overlap-induced and a quadrupolar-induced profile. The fitting parameters were determined from the analysis. Satisfactory agreement of the measurements with the calculated profiles is observed.
引用
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页码:339 / 343
页数:5
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