Synthesis, Crystal Structure and Luminescent Properties of [Zn(bipy)2(H2O)4]•L•3H2O

被引：0

作者：

Chen You-Cun ^{[1
]}

Shen Fei ^{[1
]}

Wang Yan ^{[1
,2
]}

Xu Jun-Jun ^{[1
]}

Wang Kuai-Bing ^{[1
]}

机构：

[1] Anqing Normal Univ, Sch Chem & Chem Engn, Anhui Prov Lab Optoelect & Magnetism Funct Mat, Anqing 246011, Peoples R China

[2] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

CHINESE JOURNAL OF STRUCTURAL CHEMISTRY | 2011年 / 30卷 / 09期

基金：

中国国家自然科学基金;

关键词：

zinc(II) complex; crystal structure; pi-pi interactions; hydrogen bonds; METAL-ORGANIC FRAMEWORK; SILVER(I); COPPER(II); CLUSTERS; CHAINS; SITES;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel coordination complex [Zn(bipy)(2)(H2O)(4)]center dot L center dot 3H(2)O (1, bipy = 4,4'-bipyridine, LHNa = aniline-2,5-disulfonic acid monosodium salt) has been synthesized from LHNa by using hydrothermal method and structurally characterized. The result indicates that complex 1 belongs to the monoclinic system, space group P2(1)/c with a = 20.392(3), b = 7.4052(12), c = 23.843(3) angstrom, beta = 116.253(10)degrees, V = 3.2291(8) angstrom(3), Z = 4, D-c = 1.553 g center dot cm(-3), mu = 0.962 mm(-1), F(000) = 1568, and the final R = 0.0497 and wR = 0.1290. The complex 1 has a 0-D discrete structure, and generates an infinite 3-D network with the aid of O-H center dot center dot center dot O hydrogen bonds and pi-pi interactions.

引用

页码：1251 / 1256

页数：6

共 29 条

[1] Probing the Lewis acidity and catalytic activity of the metal-organic framework [Cu3(btc)2] (BTC = benzene-1,3,5-tricarboxylate) [J].