Precursor-controlled formation of novel carbon/metal and carbon/metal oxide nanocomposites

被引:189
作者
Zhi, Linjie [1 ]
Hu, Yong-Sheng [2 ]
El Hamaoui, Bassem [1 ]
Wang, Xuan [1 ]
Lieberwirth, Ingo [1 ]
Kolb, Ute [3 ]
Maier, Joachim [2 ]
Muellen, Klaus [1 ]
机构
[1] Max Planck Inst Polymer Res, D-55128 Mainz, Germany
[2] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
[3] Johannes Gutenberg Univ Mainz, Inst Phys Chem, D-55128 Mainz, Germany
关键词
D O I
10.1002/adma.200702654
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Precursor-controlled thermolysis has been developed to specifically prepare structured carbonaceous materials (see figure) by using simple, but structurally defined, organic-cobalt complexes as starting compounds. The carbon-metal nanocomposites show excellent lithium storage properties as an anode material in lithium-ion batteries after controllable oxidation. They may also be useful as catalysts for fuel cells and other heterocatalytic reactions and as sensors for detecting chemicals and biomaterials.
引用
收藏
页码:1727 / +
页数:6
相关论文
共 49 条
  • [1] Nanostructured materials for advanced energy conversion and storage devices
    Aricò, AS
    Bruce, P
    Scrosati, B
    Tarascon, JM
    Van Schalkwijk, W
    [J]. NATURE MATERIALS, 2005, 4 (05) : 366 - 377
  • [2] Large-scale synthesis of perpendicularly aligned helical carbon nanotubes
    Bajpai, V
    Dai, LM
    Ohashi, T
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (16) : 5070 - 5071
  • [3] Barsukov I. V., 2006, NEW CARBON BASED MAT
  • [4] COBALT-CATALYZED GROWTH OF CARBON NANOTUBES WITH SINGLE-ATOMIC-LAYERWALLS
    BETHUNE, DS
    KIANG, CH
    DEVRIES, MS
    GORMAN, G
    SAVOY, R
    VAZQUEZ, J
    BEYERS, R
    [J]. NATURE, 1993, 363 (6430) : 605 - 607
  • [5] Synthesis, characterization, and li-electrochemical performance of highly porous Co3O4 powders
    Binotto, G.
    Larcher, D.
    Prakash, A. S.
    Urbina, R. Herrera
    Hegde, M. S.
    Tarascon, J-M.
    [J]. CHEMISTRY OF MATERIALS, 2007, 19 (12) : 3032 - 3040
  • [6] Alternative supports for the preparation of catalysts for low-temperature fuel cells: the use of carbon nanotubes
    Carmo, M
    Paganin, VA
    Rosolen, JM
    Gonzalez, ER
    [J]. JOURNAL OF POWER SOURCES, 2005, 142 (1-2) : 169 - 176
  • [7] Carbon nanotubule membranes for electrochemical energy storage and production
    Che, GL
    Lakshmi, BB
    Fisher, ER
    Martin, CR
    [J]. NATURE, 1998, 393 (6683) : 346 - 349
  • [8] One-dimensional porous carbon/platinum composites for nanoscale electrodes
    Cui, Guanglei
    Zhi, Linjie
    Thomas, Arne
    Kolb, Ute
    Lieberwirth, Ingo
    Muellen, Klaus
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2007, 46 (19) : 3464 - 3467
  • [9] A novel approach towards carbon-Ru electrodes with mesoporosity for supercapacitors
    Cui, Guanglei
    Zhi, Linjie
    Thomas, Arne
    Lieberwirth, Ingo
    Kolb, Ute
    Muellen, Klaus
    [J]. CHEMPHYSCHEM, 2007, 8 (07) : 1013 - 1015
  • [10] Uniform carbon and carbon/cobalt nanostructures by solid-state thermolysis of polyphenylene dendrimer/cobalt complexes
    El Hamaoui, B
    Zhi, LJ
    Wu, JS
    Kolb, U
    Müllen, K
    [J]. ADVANCED MATERIALS, 2005, 17 (24) : 2957 - +