4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium 2-(2-phenylethyl)benzoate

被引：6
|
作者：
Betz, Richard [1 ]
Gerber, Thomas [1 ]
Hosten, Eric [1 ]
Dayananda, Alaloor S. [2 ]
Yathirajan, Hemmige S. [2 ]
机构：
[1] Nelson Mandela Metropolitan Univ, Dept Chem, ZA-6031 Port Elizabeth, South Africa
[2] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2011年 / 67卷
关键词：
GRAPH-SET ANALYSIS; DIPICRATE; CRYSTALS; PATTERNS;
D O I：
10.1107/S160053681103902X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The asymmetric unit of the title salt, C17H19F2N2+center dot C15H13O2-, derived from a 1,4-diazacyclohexane derivative and a carboxylic acid, contains two formula units. The cation is protonated at the secondary amine functionality. The six-membered heterocycles adopt chair conformations. The fluorophenyl rings in the two cations make dihedral angles of 77.21 (19) and 78.8 (2)degrees while the aromatic rings in the anions enclose angles of 69.5 (2) and 69.9 (2)degrees. In the crystal, classical N-H center dot center dot center dot O hydrogen bonds as well as C-H center dot center dot center dot F and C-H center dot center dot center dot O contacts connect the entities into layers parallel to ac.
引用
收藏
页码：O2783 / +
页数：22
相关论文
共 50 条
  • [1] 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium picrate
    Betz, Richard
    Gerber, Thomas
    Hosten, Eric
    Dayananda, Alaloor S.
    Yathirajan, Hemmige S.
    Narayana, Badiadka
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2587 - U1983
  • [2] 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium bis(trichloroacetate) 0.4-hydrate
    Dayananda, A. S.
    Yathirajan, H. S.
    Floerke, Ulrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O968 - +
  • [3] 4-[Bis(4-fluorophenyl)methyl]piperazin-1-ium 2-hydroxybenzoate 2- hydroxy-benzoic acid monosolvate
    Dayananda, A. S. e
    Yathirajan, H. S.
    Floerke, Ulrich
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1180 - +
  • [4] 4-(2-Azaniumylethyl)piperazin-1-ium bis(perchlorate)
    Reisi, Mohammad Reza
    Salga, Muhammad Saleh
    Khaledi, Hamid
    Ali, Hapipah Mohd
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2400 - U874
  • [5] Syntheses and crystal structures of 4-(4-nitrophenyl)piperazin-1-ium benzoate monohydrate and 4-(4-nitrophenyl)piperazin-1-ium 2-carboxy-4,6-dinitrophenolate
    Prasad, Holehundi J. Shankara
    Devaraju
    Vinaya
    Yathirajan, Hemmige S.
    Parkin, Sean R.
    Glidewell, Christopher
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 : 840 - +
  • [6] 4-(2-Pyridyl)piperazin-1-ium chloride
    Sadiq-ur-Rehman
    Saeed, Sadia
    Ali, Saqib
    Shahzadi, Saira
    Helliwell, Madeleine
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2007, 63 : O4526 - U3353
  • [7] 1-{4-[Bis(4-fluorophenyl)methyl]-piperazin-1-yl}ethanone
    Dayananda, A. S.
    Yathirajan, H. S.
    Keeley, Amanda C.
    Jasinski, Jerry P.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O2237 - +
  • [8] 4-(Methylsulfonyl)piperazin-1-ium chloride
    Fun, Hoong-Kun
    Yeap, Chin Sing
    Kumar, C. S. Chidan
    Yathirajan, H. S.
    Narayana, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O361 - U2473
  • [9] 4-(4-Chlorophenyl)-4-hydroxypiperidinium 2-(2-phenylethyl)benzoate
    Fun, Hoong-Kun
    Hemamalini, Madhukar
    Siddaraju, B. P.
    Yathirajan, H. S.
    Narayana, B.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1726 - U1033
  • [10] 1-[Bis(4-fluorophenyl)methyl]-4-[2-(2-methylphenoxy)ethyl]piperazine
    Dai, Zhao-Hui
    Zhong, Yan
    Wu, Bin
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2012, 68 : O1077 - +
12345