Bis(tetraphenylphosphonium) bis[N-(trifluoromethylsulfonyl)dithiocarbimato(2-)-κ2S,S′]zincate(II)

被引：1
|
作者：
Pinto, Paula S. [2 ]
Rubinger, Mayura M. M. [2 ]
Guilardi, Silvana [1 ]
Paixao, Drielly A. [1 ]
Oliveira, Marcelo R. L. [2 ]
机构：
[1] Univ Fed Uberlandia, Inst Quim, Uberlandia, MG, Brazil
[2] Univ Fed Vicosa, Dept Quim, Vicosa, MG, Brazil
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷
关键词：
SPECTROSCOPIC CHARACTERIZATION; ZINC(II) COMPLEXES; CRYSTAL-STRUCTURE;
D O I：
10.1107/S160053681105207X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title salt, (C24H20P)(2)[Zn(C2F3NO2S3)(2)], consists of a complex dianion and two tetraphenylphosphonium cations. The Zn-II ion displays a distorted tetrahedral coordination environment with four S atoms from two S, S'-chelated N-(trifluoromethylsulfonyl)dithiocarbimate anions. In the crystal, besides the ionic interaction of the oppositely charged ions, intermolecular C-H center dot center dot center dot O interactions between cations and anions are observed. One of the cations interacts with an inversion-related equivalent by pi-pi stacking between phenyl rings, with a centroid-centroid distance of 3.932 (4) angstrom.
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收藏
页码：M33 / +
页数：16
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