Bis(tetraphenylphosphonium) bis[N-(trifluoromethylsulfonyl)dithiocarbimato(2-)-κ2S,S′]zincate(II)

被引：1

作者：

Pinto, Paula S. ^{[2
]}

Rubinger, Mayura M. M. ^{[2
]}

Guilardi, Silvana ^{[1
]}

Paixao, Drielly A. ^{[1
]}

Oliveira, Marcelo R. L. ^{[2
]}

机构：

[1] Univ Fed Uberlandia, Inst Quim, Uberlandia, MG, Brazil

[2] Univ Fed Vicosa, Dept Quim, Vicosa, MG, Brazil

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2012年 / 68卷

关键词：

SPECTROSCOPIC CHARACTERIZATION; ZINC(II) COMPLEXES; CRYSTAL-STRUCTURE;

D O I：

10.1107/S160053681105207X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title salt, (C24H20P)(2)[Zn(C2F3NO2S3)(2)], consists of a complex dianion and two tetraphenylphosphonium cations. The Zn-II ion displays a distorted tetrahedral coordination environment with four S atoms from two S, S'-chelated N-(trifluoromethylsulfonyl)dithiocarbimate anions. In the crystal, besides the ionic interaction of the oppositely charged ions, intermolecular C-H center dot center dot center dot O interactions between cations and anions are observed. One of the cations interacts with an inversion-related equivalent by pi-pi stacking between phenyl rings, with a centroid-centroid distance of 3.932 (4) angstrom.

引用

页码：M33 / +

页数：16

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