A novel 1D independent metal-organic nanotube based on cyclotriveratrylene ligand

被引：31

作者：

Yu, Jin-Tao ^{[1
]}

Sun, Junliang ^{[2
]}

Huang, Zhi-Tang ^{[1
]}

Zheng, Qi-Yu ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Stockholm Univ, Struct Chem & Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

COORDINATION POLYMERS; RETICULAR SYNTHESIS; AMINO-ACID; PORE-SIZE; FRAMEWORKS; DESIGN; FUNCTIONALITY; CRYPTOPHANES; ADSORPTION; COMPLEXES;

D O I：

10.1039/c1ce05316g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel nanotubular metal-organic framework [Cu3L2(EtOH)(Py)(2)(H2O)(2)]center dot 9DEF center dot 8H(2)O (CTV-Cu) was prepared by assembly of the rigid, trigonal pyramidal ligand tri-(4-carboxy-phenyl)-trimethoxycyclobenzylene (H3L) and Cu(NO3)(2)center dot 3H(2)O via solvothermal reaction. The Cu(II) ions in the crystal serve as square and linear molecular building blocks, thus forming a framework with ternary topology. One single open-ended nanotube contains two identical orthogonally interpenetrated two-nodal nets. This framework exhibits permanent microporosity and relatively high surface area.

引用

页码：112 / 115

页数：4

共 50 条

[21] Luminescent and magnetic properties of three novel metal-organic polymers based on a semi-rigid tripodal carboxylic ligand
Zhang, Jie
Huo, Liang-Qin
Gao, Ling-Ling
Wang, Xiao-Qing
Fan, Li-Ming
Fang, Ke-Gong
Hu, Tuo-Ping
POLYHEDRON, 2017, 137 : 238 - 245
[22] Topological Diversification in Metal-Organic Frameworks: Secondary Ligand and Metal Effects
Liu, Jian-Qiang
Wang, Yao-Yu
Zhang, Ya-Nan
Liu, Ping
Shi, Qi-Zhen
Batten, Stuart R.
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2009, (01) : 147 - 154
[23] Properties of Aliphatic Ligand-Based Metal-Organic Frameworks
Demakov, Pavel A.
POLYMERS, 2023, 15 (13)
[24] Construction of Metal-Organic Frameworks with 1D Chain, 2D Grid, and 3D Porous Framework Based on a Flexible Imidazole Ligand and Rigid Benzenedicarboxylates
He, Haiyan
Collins, David
Dai, Fangna
Zhao, Xiaoliang
Zhang, Guoqing
Ma, Huiqing
Sun, Daofeng
CRYSTAL GROWTH & DESIGN, 2010, 10 (02) : 895 - 902
[25] Structural variation from 1D to 3D: effect of metal centers on the construction of metal-organic coordination polymers with N-(1H-tetrazol-5-yl)benzamide ligand
Wang, Y. -B.
Liu, D. -S.
Pan, T. -H.
Liang, Q.
Huang, X. -H.
Wu, S. -T.
Huang, C. -C.
CRYSTENGCOMM, 2010, 12 (11): : 3886 - 3893
[26] Two 2D Metal-organic Networks Based on a Rigid Imidazolate/Sulfonate Functionalized Ligand - Effect of the Coordination Modes of the Ligand on Crystal Structures
Wang, Xiu-Ying
Xu, Long
Liu, Rui-Bin
Liu, Shu-Qin
Yang, Wen-Bo
Zhang, Jian-Jun
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2012, 638 (06): : 1006 - 1011
[27] Two independent, 1-D metal-organic nanotubes based on rings or helical chain units
Zhu, Xia
Zhao, Shan
Peng, Yan-Fen
Li, Bao-Long
Li, Hai-Yan
JOURNAL OF COORDINATION CHEMISTRY, 2014, 67 (08) : 1317 - 1331
[28] Structural diversity through ligand flexibility: two novel metal-organic nets via ligand-to-ligand cross-linking of "paddlewheels"
Qiu, Wenge
Perman, Jason A.
Wojtas, Lukasz
Eddaoudi, Mohamed
Zaworotko, Michael J.
CHEMICAL COMMUNICATIONS, 2010, 46 (46) : 8734 - 8736
[29] A flexible zwitterion ligand based lanthanide metal-organic framework for luminescence sensing of metal ions and small molecules
Wen, Rong-Mei
Han, Song-De
Ren, Guo-Jian
Chang, Ze
Li, Yun-Wu
Bu, Xian-He
DALTON TRANSACTIONS, 2015, 44 (24) : 10914 - 10917
[30] Solid-Phase Extraction of Organic Dyes on Mixed-Ligand Zr(IV) Metal-Organic Framework
Kharisov, Boris
Kharissova, Oxana
Zhinzhilo, Vladimir
Bryantseva, Julia
Uflyand, Igor
APPLIED SCIENCES-BASEL, 2022, 12 (23):

← 1 2 3 4 5 →