A novel 1D independent metal-organic nanotube based on cyclotriveratrylene ligand

被引：31

作者：

Yu, Jin-Tao ^{[1
]}

Sun, Junliang ^{[2
]}

Huang, Zhi-Tang ^{[1
]}

Zheng, Qi-Yu ^{[1
]}

机构：

[1] Chinese Acad Sci, Beijing Natl Lab Mol Sci, CAS Key Lab Mol Recognit & Funct, Inst Chem, Beijing 100190, Peoples R China

[2] Stockholm Univ, Struct Chem & Berzelii Ctr EXSELENT Porous Mat, SE-10691 Stockholm, Sweden

来源：

CRYSTENGCOMM | 2012年 / 14卷 / 01期

基金：

中国国家自然科学基金;

关键词：

COORDINATION POLYMERS; RETICULAR SYNTHESIS; AMINO-ACID; PORE-SIZE; FRAMEWORKS; DESIGN; FUNCTIONALITY; CRYPTOPHANES; ADSORPTION; COMPLEXES;

D O I：

10.1039/c1ce05316g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel nanotubular metal-organic framework [Cu3L2(EtOH)(Py)(2)(H2O)(2)]center dot 9DEF center dot 8H(2)O (CTV-Cu) was prepared by assembly of the rigid, trigonal pyramidal ligand tri-(4-carboxy-phenyl)-trimethoxycyclobenzylene (H3L) and Cu(NO3)(2)center dot 3H(2)O via solvothermal reaction. The Cu(II) ions in the crystal serve as square and linear molecular building blocks, thus forming a framework with ternary topology. One single open-ended nanotube contains two identical orthogonally interpenetrated two-nodal nets. This framework exhibits permanent microporosity and relatively high surface area.

引用

页码：112 / 115

页数：4

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