Physical properties of the de-lithiated Li2-xRuO3 with the layered structure

被引：30
作者：
Kobayashi, H
Kanno, R
Kawamoto, Y
Tabuchi, M
Nakamura, O
机构：
[1] KOBE UNIV,FAC SCI,DEPT CHEM,NADA KU,KOBE,HYOGO 657,JAPAN
[2] OSAKA NATL RES INST,IKEDA,OSAKA 563,JAPAN
来源：
SOLID STATE IONICS | 1996年 / 86-8卷
关键词：
lithium deintercalation; oxidation; layered oxides;
D O I：
10.1016/0167-2738(96)00194-4
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The layered oxides, Li2-xRuO3, were synthesized by chemical oxidation using I-2 in CH3CN and their electrical and magnetic properties were investigated. The lithium deintercalation from Li2RuO3 caused the decrease of resistivity and the change in magnetic property from Curie-Weiss paramagnetism at x=0.0 to nearly temperature-independent paramagnetism at x=1.0. The relationship between oxidation states of the ruthenium ions and its physical properties was discussed.
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页码：859 / 863
页数：5
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