Stereoconvergent approach to each of the stereoisomeric hydroxydiquinanes based on the anionic [1,3] rearrangement of bicyclo[3.2.1]oct-6-en-2-ols

被引：3

作者：

Hashimoto, H

Seki, K

Ueno, M

Sato, T

Uyehara, T ^{[1
]}

机构：

[1] Utsunomiya Univ, Fac Engn, Dept Appl Chem, Utsunomiya, Tochigi 3218585, Japan

[2] Tohoku Univ, Fac Sci, Instrumental Anal Ctr Chem, Sendai, Miyagi 9808578, Japan

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 03期

关键词：

rearrangements; carbanions; potassium and compounds; solvents and solvent effects;

D O I：

10.1016/S0040-4039(98)02389-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The anionic [1,3] rearrangement of both stereoisomeric bicyclo[3.2.1]oct-6-en-2-ols by treatment with KN(TMS)(2) in toluene or in diglyme took place as a stereoconvergent route giving each of the stereoisomeric hydroxydiquinanes. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：511 / 514

页数：4

共 12 条

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