Kinetics of the catalytic oxidation of lean trichloroethylene in air over Pd/Alumina

被引：17

作者：

Aranzabal, A ^{[1
]}

Ayastuy-Arizti, JL ^{[1
]}

González-Marcos, JA ^{[1
]}

González-Velasco, JR ^{[1
]}

机构：

[1] Univ Basque Country, Fac Sci, Dept Chem Engn, EHU, E-48080 Bilbao, Spain

来源：

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH | 2003年 / 42卷 / 24期

关键词：

D O I：

10.1021/ie030286r

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

Kinetic modeling of the catalytic oxidation of trichloroethylene (TCE) over a palladium supported on alumina was evaluated. On the basis of previous studies on the effect of temperature, inlet TCE and oxygen concentrations, and the space velocity on the reaction rate, a five-step reaction network scheme, based on an Eley-Rideal-type mechanism, provided an accurate correlation of the experimental data, determined by a nonlinear least-squares regression.

引用

页码：6007 / 6011

页数：5

共 24 条

[1]

ARANZABAL A, 2000, THESIS U PAIS VASCO

[2]

ARANZABAL A, 2003, IN PRESS J CATAL

[3] Interaction of chlorinated ethylenes with chromium exchanged zeolite Y: An in situ FT-IR study [J].