Fixed-bed column and batch reactors performance in removal of diazinon pesticide from aqueous solutions by using walnut shell-modified activated carbon

This paper evaluates adsorption of diazinon pesticide from aqueous solution onto walnut shell-modified activated carbon using fixed-bed column and batch system. Contact time, initial concentration, and pH were considered as variable parameters to obtain maximum adsorption capacity using batch technique. The pseudo-first-order, the pseudo-second-order, and Webber and Morris models were chosen to analyze adsorption kinetic data. The results indicated that adsorption process followed closely the pseudo-second-order kinetic model. The equilibrium adsorption data fitted the Freundlich isotherm well, with K-f = 53.82, n = 1.98, and R-2 = 0.9966. For continuous fixed-bed column studies, the effect of inlet concentration (15-40 mg.lit(-1)), flow rate (9.5-16.5 lit.h(-1)), and bed height (10-30 cm) was investigated. Results showed that increase in inlet concentration and also bed height lead to increase of bed capacity. In addition, changes in flow rate from 9.5 to 14.5 lit.h(-1) caused a decrease in bed capacity. However, a minor increase in bed capacity was observed via an increase in flow rate from 14.5 to 16.5 lit.h(-1). The highest bed capacities were 34.98 and 34.31 mg.g(-1) for the same initial concentration of 40 mg.lit(-1), flow rates of 12 and 9.5 lit.h(-1), and bed heights of 30 and 20 cm, respectively. Dynamic behavior of column was investigated by Bohart-Adams and Yoon-Nelson models. According to obtained results, Yoon-Nelson model can describe well the adsorption process. The findings of the current study show that the walnut shell-modified activated carbon can be successfully applied to remove diazinon pesticide from aqueous solution. (C) 2018 Elsevier B.V. All rights reserved.