The luminescence properties of Sm2+ doped sodium barium strontium phosphate

被引:12
作者
Huang, Yanlin [2 ]
Kai, Weifang [2 ]
Jang, Kiwan [1 ]
Lee, Ho Sueb [1 ]
Wang, Xigang [2 ]
Zhang, Ying [2 ]
Qin, Dake [2 ]
Jiang, Chanfang [2 ]
机构
[1] Changwon Natl Univ, Dept Phys, Chang Won 641773, South Korea
[2] Soochow Univ, Sch Mat Engn, Suzhou 215021, Peoples R China
关键词
luminescence; optical materials and properties; phosphors; minerals; Sm(2+) ions; reduction;
D O I
10.1016/j.matlet.2007.10.041
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Sm(3+) ions doped NaSm(0.01)Ba(0.78)Sr(0.21) (PO(4)) was prepared by high-temperature solid-state reaction method. Sm(2+) ions were obtained by X-ray irradiation reduction. The samples were investigated by X-ray diffraction, photoluminescence, and decay curves measurements. It is found that the conversion of Sm(3+)-> Sm(2+) after X-ray irradiation is very efficient in this phosphate. NaSm(0.01)Ba(0.78)Sr(0.21) (PO(4)) is a suitable host for Sm(3+) -> Sm(2+) conversion. The emission of Sm(2+) in this host after excitation into the 4f(5)5d(1) levels shows (5)D(0)-> (7)F(j) (J= 0, 1, 2) emission together with the broad 5d -> 4f emission band at room temperature, while only the (5)D(0)-> (7)F(j), (J=0, 1, 2) emission is observed at lower temperature. (c) 0 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:1913 / 1915
页数:3
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