5-Membered N-heterocyclic compounds by dimethyl carbonate chemistry

被引：27

作者：

Arico, Fabio ^{[1
]}

Toniolo, Umberto ^{[1
]}

Tundo, Pietro ^{[1
]}

机构：

[1] Univ Ca Foscari Venezia, Dipartimento Sci Ambientali Informat & Stat, I-30123 Venice, Italy

来源：

GREEN CHEMISTRY | 2012年 / 14卷 / 01期

关键词：

AMINES;

D O I：

10.1039/c1gc15698e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aliphatic and aromatic 1,4-bifunctional compounds bearing a primary alcoholic function and an amine can be efficiently cyclised with dimethyl carbonates in the presence of a base to achieve 5-membered N-heterocyclic compounds. This novel synthetic pathway is quantitative, one-pot and green as it does not involve the use of chlorine solvents or reagent.

引用

页码：58 / 61

页数：4

共 7 条

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[7] β-Enaminone Synthesis from 1,3-Dicarbonyl Compounds and Aliphatic and Aromatic Amines Catalyzed by Iron Complexes of Fused Bicyclic Imidazo[1,5-a]pyridine Derived N-Heterocyclic Carbenes
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