Cross-section and selection rules in surface-enhanced hyper Raman scattering

被引：16
作者：
Polubotko, A. M. [1 ]
Smirnov, V. P. [2 ]
机构：
[1] Russian Acad Sci, AF Ioffe Physicotech Inst, St Petersburg 194021, Russia
[2] State Univ Informat Technol Mech & Opt, St Petersburg 197101, Russia
来源：
JOURNAL OF RAMAN SPECTROSCOPY | 2012年 / 43卷 / 03期
关键词：
surface-enhanced hyper Raman scattering (SEHRS); SEHR cross-section; selection rules; forbidden lines; PICOSECOND LASER; SPECTROSCOPY; PYRIDINE; MOLECULES; SILVER; PYRAZINE; COLLOIDS; SERS;
D O I：
10.1002/jrs.3032
中图分类号：
O433 [光谱学];
学科分类号：
0703 ; 070302 ;
摘要：
The expression for the surface-enhanced hyper Raman scattering (SEHRS) cross-section of symmetrical molecules within the framework of the dipolequadrupole theory is presented. It is formed by contributions that depend on various dipole and quadrupole moments. The enhancement coefficients for the quadrupole enhancement mechanism in some limited cases can reach a value 10(30). It is demonstrated that the contributions follow some selection rules. Qualitative classification of the contributions based on the enhancement degree is given. It is demonstrated that the SEHR spectra of pyrazine and pyridine can be explained by the presented theory. Copyright (C) 2011 John Wiley & Sons, Ltd.
引用
收藏
页码：380 / 388
页数：9
相关论文
共 15 条
[1]  
Baranov A.V., 1982, ZH EKSP TEOR FIZI PI, V36, P277
[2]   A SURFACE ENHANCED HYPER-RAMAN SCATTERING STUDY OF PYRIDINE ADSORBED ONTO SILVER - EXPERIMENT AND THEORY [J].
GOLAB, JT ;
SPRAGUE, JR ;
CARRON, KT ;
SCHATZ, GC ;
VANDUYNE, RP .
JOURNAL OF CHEMICAL PHYSICS, 1988, 88 (12) :7942-7951
[3]   NONLINEAR SURFACE-ENHANCED SPECTROSCOPY OF SILVER COLLOIDS AND PYRIDINE - HYPER-RAMAN AND 2ND-HARMONIC SCATTERING [J].
JOHNSON, CK ;
SOPER, SA .
JOURNAL OF PHYSICAL CHEMISTRY, 1989, 93 (21) :7281-7285
[4]   Surface-enhanced hyper-Raman spectroscopy (SEHRS) and surface-enhanced Raman spectroscopy (SERS) studies of pyrazine and pyridine adsorbed on silver electrodes [J].
Li, WH ;
Li, XY ;
Yu, NT .
CHEMICAL PHYSICS LETTERS, 1999, 305 (3-4) :303-310
[5]   Surface-enhanced hyper-Raman and surface-enhanced Raman scattering from molecules adsorbed on nanoparticles-on-smooth-electrode (NOSE) substrate - I. Pyridine, pyrazine and benzene [J].
Li, XY ;
Huang, QJ ;
Petrov, VI ;
Xie, YT ;
Luo, I ;
Yu, XY ;
Yan, YJ .
JOURNAL OF RAMAN SPECTROSCOPY, 2005, 36 (6-7) :555-573
[6]   SURFACE-ENHANCED HYPER-RAMAN SPECTROSCOPY WITH A PICOSECOND LASER - GOLD AND COPPER COLLOIDS [J].
LIPSCOMB, LA ;
NIE, S ;
FENG, S ;
YU, NT .
CHEMICAL PHYSICS LETTERS, 1990, 170 (5-6) :457-461
[7]   SURFACE-ENHANCED HYPER-RAMAN SCATTERING FROM SO32- ADSORBED ON AG POWDER [J].
MURPHY, DV ;
VONRABEN, KU ;
CHANG, RK ;
DORAIN, PB .
CHEMICAL PHYSICS LETTERS, 1982, 85 (01) :43-47
[8]   RESONANT AND NONRESONANT SURFACE-ENHANCED HYPER-RAMAN SPECTROSCOPY WITH A PICOSECOND LASER - EFFECT OF THE EXCITATION PULSE WIDTH [J].
NIE, SM ;
LIPSCOMB, LA ;
FENG, S ;
YU, NT .
CHEMICAL PHYSICS LETTERS, 1990, 167 (1-2) :35-40
[9]  
Pockrand I., 1984, SPRINGER TRACTS MODE, V104
[10]  
Polubotko A., 2009, DIPOLE QUADRUPOLE TH
12