Kinetics on the axial coordination reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol

被引：1

作者：

Feng, HX ^{[1
]}

Zhu, ZA ^{[1
]}

Wang, CZ ^{[1
]}

Ruan, WJ ^{[1
]}

Li, Y ^{[1
]}

Chen, YT ^{[1
]}

机构：

[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China

来源：

ACTA PHYSICO-CHIMICA SINICA | 1999年 / 15卷 / 02期

关键词：

Co(II)-phthalocyanine; thiol; kinetics of axial coordinational reaction; stopped flow method; mechanism;

D O I：

10.3866/PKU.WHXB19990214

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The kinetic studies on the axial coordination reaction of Co(II)-2,9,16,23-tetracaboxyphthalocyanine with 2-mercaptoethanol in aqueous solution were studied by stopped flow method. A general mechanism was proposed and the kinetic parameters were obtained by non-liner and liner least-squares program. The effects of temperature and pH on the reaction were investigated in this paper.

引用

页码：167 / 172

页数：6

共 17 条

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