Catalytic Asymmetric Synthesis of Isochroman Derivatives

被引：20

作者：

Tamanna ^{[1
]}

Kumar, Mukesh ^{[2
]}

Joshi, Kavita ^{[1
]}

Chauhan, Pankaj ^{[1
]}

机构：

[1] Indian Inst Technol Jammu Jagti, Dept Chem, NH 44, Jammu 181221, Jammu & Kashmir, India

[2] Sahu Jain Coll, Dept Chem, Najibabad 246763, Bijnor, India

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2020年 / 362卷 / 10期

关键词：

asymmetric catalysis; isochromanones; isochromans; isochromenes; organic catalysis; OXA-MICHAEL REACTION; ONE-POT SYNTHESIS; ENANTIOSELECTIVE SYNTHESIS; BRONSTED ACID; DIASTEREOSELECTIVE SYNTHESIS; ORGANOCATALYTIC SYNTHESIS; CARBOXYLIC-ACIDS; BENZYLIC ETHERS; CONSTITUENTS; HYDRANGENOL;

D O I：

10.1002/adsc.202000243

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The isochroman scaffold constitutes an important structural unit, which is present in various bioactive natural products and synthetic pharmaceutical compounds exhibiting wide arrays of biological properties. Hence the synthesis of this class of heterocyclic compounds in a stereoselective fashion is highly significant and desirable. In the last decade, a substantial advancement has been witnessed ln the catalytic asymmetric synthesis of isochroman derivatives by employing metal catalysts bearing chiral ligands or by chiral metal-free organocatalysts. This review aims to provide an overview of the transition metal-catalyzed and organocatalyzed asymmetric syntheses of isochroman derivatives including isochromenes and isochromanones.

引用

页码：1907 / 1926

页数：20

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