Electrochemically Generated ArS(ArSSAr)+B(C6F5)4- as an Activator of Thioglycosides for Glycosylation

被引：17

作者：

Saito, Kodai ^{[1
]}

Saigusa, Yoshihiro ^{[1
]}

Nokami, Toshiki ^{[1
]}

Yoshida, Jun-ichi ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Synthet Chem & Biol Chem, Nishikyo Ku, Kyoto 6158510, Japan

来源：

CHEMISTRY LETTERS | 2011年 / 40卷 / 07期

关键词：

ALKOXYCARBENIUM ION POOLS; OLIGOSACCHARIDE SYNTHESIS; ITERATIVE GLYCOSYLATION; CHEMICAL GLYCOSYLATION; CATION; STRATEGIES;

D O I：

10.1246/cl.2011.678

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Electrochemically generated ArS(ArSSAr)(+) was found to be an effective activator for glycosylation of thioglycosides. Efficiency of the reaction strongly depends on the nature of the counter anion, and B(C6F5)(4)(-) was the most effective among those examined. The method was applicable to various glyocosyl donors including thiogalactosides and thiomannosides and various acceptors including those having secondary hydroxy groups.

引用

页码：678 / 679

页数：2

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