Prediction and experimental verification of HFC-134a adsorption by activated carbons

被引:10
作者
Lin, SH [1 ]
Lin, RC [1 ]
机构
[1] Yuan Ze Univ, Dept Chem Engn, Chungli 320, Taiwan
来源
JOURNAL OF ENVIRONMENTAL SCIENCE AND HEALTH PART A-TOXIC/HAZARDOUS SUBSTANCES & ENVIRONMENTAL ENGINEERING | 1999年 / 34卷 / 01期
关键词
HFC-134a; activated carbons; column adsorption; theoretical predictions;
D O I
10.1080/10934529909376830
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
Theoretical and experimental investigations were conducted on the adsorption characteristics of 1,1,1,2-tetrafluoroethane (HFC-134a) by granular and extruded activated carbons (GAC and EAC). HFC-134a is currently regarded as an excel-lent replacement for CFC-12 (Freon 12), a refrigerant previously used in all automobiles and many cooling systems. Experimental results of column adsor-ption were employed to verify the theoretical breakthrough curves generated from the pro-posed model and excellent model fit of the breakthrough curves of HCFC-134a adsorption were obtained. Investigations were also made on the effects of gas velocity, inlet HFC-134a concentration and operating temperature on the adsorption efficiency.
引用
收藏
页码:183 / 200
页数:18
相关论文
共 14 条
  • [1] CATALYTIC DESTRUCTION OF CHLOROFLUOROCARBONS AND TOXIC CHLORINATED HYDROCARBONS
    BICKLE, GM
    SUZUKI, T
    MITARAI, Y
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1994, 4 (2-3) : 141 - 153
  • [2] SONOCHEMICAL DESTRUCTION OF CFC-11 AND CFC-113 IN DILUTE AQUEOUS-SOLUTION
    CHEUNG, HM
    KURUP, S
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (09) : 1619 - 1622
  • [3] DECOMPOSITION OF DICHLORODIFLUOROMETHANE ON PO4-ZRO2 CATALYST
    IMAMURA, S
    SHIMIZU, H
    HAGA, T
    TSUJI, S
    UTANI, K
    WATANABE, M
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1993, 32 (12) : 3146 - 3149
  • [4] DECOMPOSITION OF DICHLORODIFLUOROMETHANE ON BPO4 CATALYST
    IMAMURA, S
    IMAKUBO, K
    FURUYOSHI, S
    JINDAI, H
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1991, 30 (10) : 2355 - 2358
  • [5] AN INVESTIGATION OF CFC12 (CCL2F2) DECOMPOSITION ON TIO2 CATALYST
    KARMAKAR, S
    GREENE, HL
    [J]. JOURNAL OF CATALYSIS, 1995, 151 (02) : 394 - 406
  • [6] OXIDATIVE DESTRUCTION OF CHLOROFLUOROCARBONS (CFC11 AND CFC12) BY ZEOLITE CATALYSTS
    KARMAKAR, S
    GREENE, HL
    [J]. JOURNAL OF CATALYSIS, 1992, 138 (01) : 364 - 376
  • [7] DECREASING OZONE CAUSES HEALTH CONCERN - CANADA FORECASTS ULTRAVIOLET-B RADIATION
    KERR, JB
    [J]. ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1994, 28 (12) : A514 - A518
  • [8] MCLINDEN MO, 1980, ASHRAE J, V29, P72
  • [9] STRATOSPHERIC SINK FOR CHLOROFLUOROMETHANES - CHLORINE ATOMIC-CATALYSED DESTRUCTION OF OZONE
    MOLINA, MJ
    ROWLAND, FS
    [J]. NATURE, 1974, 249 (5460) : 810 - 812
  • [10] CATALYTIC OXIDATIVE DECOMPOSITION OF CHLOROFLUOROCARBON (CFCS) IN THE PRESENCE OF HYDROCARBONS
    NAGATA, H
    TAKAKURA, T
    TASHIRO, S
    KISHIDA, M
    MIZUNO, K
    TAMORI, I
    WAKABAYASHI, K
    [J]. APPLIED CATALYSIS B-ENVIRONMENTAL, 1994, 5 (1-2) : 23 - 31