Syntheses and Structures of the Hexacoordinated Antimony Complexes: Ph3(C2H4O2)SbDMSO, (3-FC6H4)3(C2H4O2)SbDMSO, and (4-MeC6H4)3(C6H4O2)SbDMSO

被引：3

作者：

Sharutin, V. V. ^{[1
]}

Sharutina, O. K. ^{[1
]}

Shalabanova, N. A. ^{[1
]}

机构：

[1] Natl Res Southern Ural State Univ, Chelyabinsk, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2018年 / 44卷 / 12期

关键词：

triphenylantimony; tris(3-fluorophenyl)antimony; ethylene glycol; pyrocatechol; dimethyl sulfoxide; oxidation synthesis; hexacoordinated antimony(V) complexes; X-ray diffraction analysis; CRYSTAL-STRUCTURE; TETRAPHENYLANTIMONY;

D O I：

10.1134/S1070328418120138

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Complexes Ph-3(C2H4O2)SbDMSO (I), (3-FC6H4)(3)(C2H4O2)SbDMSO (II), and (4-MeC6H4)(3)-(C6H4O2)SbDMSO (III) are synthesized by the reactions of triarylantimony with ethylene glycol or pyrocatechol in the presence of an oxidant and dimethyl sulfoxide (DMSO). According to the X-ray diffraction analysis data, the Sb atoms in the complexes have the coordination of a distorted octahedron with the chelate cycle (C2H4O2 or C6H4O2) and two aryl groups in the equatorial plane, and the third aryl group and DMSO molecule occupy the axial positions. The CSbO axial angles are 173.59(5)degrees (I); 175.96(8)degrees, 175.93(8)degrees (II); and 174.07(8)degrees (III). The Sb?=SMe2 distances (2.346(2)-2.407(2) angstrom) considerably exceed the sum of covalent radii of the atoms.

引用

页码：765 / 771

页数：7

共 29 条

[1]

Abakumov G. A., 2007, IZV AKAD NAUK K, P1750

[2] TABLES OF BOND LENGTHS DETERMINED BY X-RAY AND NEUTRON-DIFFRACTION .1. BOND LENGTHS IN ORGANIC-COMPOUNDS [J].

ALLEN, FH ;

KENNARD, O ;

WATSON, DG ;

BRAMMER, L ;

ORPEN, AG ;

TAYLOR, R .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1987, (12) :S1-S19

[3] SYNTHESIS OF 2 TETRAPHENYLANTIMONY COMPLEXES OF PYRIDINE-N-OXIDES - CRYSTAL-STRUCTURE OF TETRAPHENYLANTIMONY (2-MERCAPTOPYRIDINE-N-OXIDE) [J].

ARVANITIS, GM ;

BERARDINI, ME ;

ACTON, TB ;

DUMAS, PE .

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 82 (1-4) :127-135

[4]

*BRUK AXS INC, 1998, SHELXTL PC VERS 5 10

[5]

Bruker SMART and SAINT-Plus, 1998, SMART SAINT PLUS VER

[6] Triphenylantimony(v) catecholates and o-amidophenolates:: Reversible binding of molecular oxygen [J].

Cherkasov, Vladimir K. ;

Abakumov, Gleb A. ;

Grunova, Ekaterina V. ;

Poddel'sky, Andrey I. ;

Fukin, Georgy K. ;

Baranov, Evgenii V. ;

Kurskii, Yury V. ;

Abakumova, Ludmila G. .

CHEMISTRY-A EUROPEAN JOURNAL, 2006, 12 (14) :3916-3927

[7]

Dodonov V.A., 1989, METALLOORGAN KHIM, V2, P1296

[8]

Dodonov V.A., 1995, IZV AKAD NAUK K, P748

[9] Synthesis and structural characterization of some complexes of hexa-coordinated antimony [J].

Dodonov, VA ;

Fedorov, AY ;

Fukin, GK ;

Zaburdyaeva, SN ;

Zakharov, LN ;

Ignatenko, AV .

MAIN GROUP CHEMISTRY, 1999, 3 (01) :15-22

[10] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

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