[P(μ-NTer)]2: A Biradicaloid That Is Stable at High Temperature

被引：132
作者：
Beweries, Torsten [2 ]
Kuzora, Rene [1 ]
Rosenthal, Uwe [2 ]
Schulz, Axel [1 ,2 ]
Villinger, Alexander [1 ]
机构：
[1] Univ Rostock, Inst Chem, D-18059 Rostock, Germany
[2] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 38期
关键词：
biradicaloids; heterocycles; main-group elements; multiple bonds; structure elucidation; ELEMENT COMPOUNDS; DERIVATIVES; RING; CHEMISTRY; BONDS; DIMER;
D O I：
10.1002/anie.201103742
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Radical protection makes a biradical: High-temperature-stable biradicaloids [P(μ-NR)]2 (R=Ter, Hyp) were isolated from [ClP(μ-NR)] 2 when mild reducing agents were employed. The bulky substituents prevent dimerization. Ter=2,6-Mes2C6H3, with Mes=2,4,6-Me3C6H2; Hyp=(Me3Si) 3Si. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：8974 / 8978
页数：5
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