A Theta-Shaped Amphiphilic Cobaltabisdicarbollide Anion: Transition From Monolayer Vesicles to Micelles

被引：148

作者：

Bauduin, Pierre ^{[1
]}

Prevost, Sylvain ^{[2
,3
]}

Farras, Pau ^{[4
]}

Teixidor, Francesc

Diat, Olivier ^{[1
]}

Zemb, Thomas ^{[1
]}

机构：

[1] CEA Marcoule, ICSM, CEA, CNRS,ENSCM,UM2,UMR 5257, F-30207 Bagnols Sur Ceze, France

[2] Tech Univ Berlin, HZB Mat & Energie, D-10623 Berlin, Germany

[3] Tech Univ Berlin, Stranski Lab, D-10623 Berlin, Germany

[4] CSIC, ICMAB, Bellaterra 08193, Spain

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 23期

关键词：

carboranes; cryo-TEM; micelles; small-angle neutron scattering; vesicles; LIPOSOMES;

D O I：

10.1002/anie.201100410

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Sandwiched: The cobaltabisdicarbollide (mono-)anion ([3,3′-Co(1,2- C2B9H11)2]-, COSAN -) forms monolayer vesicles at low concentrations in water (see picture). An increase in concentration leads to a Coulomb explosion of the closely packed vesicles into small micelles, which results in the coexistence of both aggregation states at higher concentrations. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：5298 / 5300

页数：3

共 30 条

[1]

[Anonymous], 1997, FLATLAND GEOMETRIC F, DOI DOI 10.1016/B978-044481538-5/50005-8

[2]

[Anonymous], ANGEW CHEM

[3] Vesicles and liposomes:: A self-assembly principle beyond lipids [J].

Antonietti, M ;

Förster, S .

ADVANCED MATERIALS, 2003, 15 (16) :1323-1333

[4] Combined small-angle X-ray and neutron scattering experiments for thickness characterization of ganglioside bilayers [J].

Cantú, L ;

Corti, M ;

Del Favero, E ;

Dubois, M ;

Zemb, TN .

JOURNAL OF PHYSICAL CHEMISTRY B, 1998, 102 (30) :5737-5743

[5] Interfaces and the driving force of hydrophobic assembly [J].

Chandler, D .

NATURE, 2005, 437 (7059) :640-647

[6] Surfactant behavior of "ellipsoidal" dicarbollide anions: A molecular dynamics study [J].

Chevrot, G. ;

Schurhammer, R. ;

Wipff, G. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (19) :9488-9498

[7] From nonpeptide toward noncarbon protease inhibitors:: Metallacarboranes as specific and potent inhibitors of HIV protease [J].

Cígler, P ;

Kozísek, M ;

Rezácová, P ;

Brynda, J ;

Otwinowski, Z ;

Pokorná, J ;

Plesek, J ;

Grüner, B ;

Dolecková-Maresová, L ;

Mása, M ;

Sedlácek, J ;

Bodem, J ;

Kräusslich, HG ;

Král, V ;

Konvalinka, J .

PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2005, 102 (43) :15394-15399

[8] Self-assembly of regular hollow icosahedra in salt-free catanionic solutions [J].

Dubois, M ;

Demé, B ;

Gulik-Krzywicki, T ;

Dedieu, JC ;

Vautrin, C ;

Désert, S ;

Perez, E ;

Zemb, T .

NATURE, 2001, 411 (6838) :672-675

[9]

Evans D.F., 1999, Advances in interfacial engineering series, V2nd

[10] Vesicles and vesicle gels - structure and dynamics of formation [J].

Gradzielski, M .

JOURNAL OF PHYSICS-CONDENSED MATTER, 2003, 15 (19) :R655-R697

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