Oxidative C-S Bond Cleavage of Benzyl Thiols Enabled by Visible-Light-Mediated Silver(II) Complexes

被引：23

作者：

Hong, Boseok ^{[1
]}

Aganda, Kim Christopher C. ^{[2
]}

Lee, Anna ^{[1
,2
]}

机构：

[1] Myongji Univ, Dept Chem, Yongin 17058, South Korea

[2] Myongji Univ, Dept Energy Sci & Technol, Yongin 17058, South Korea

来源：

ORGANIC LETTERS | 2020年 / 22卷 / 11期

基金：

新加坡国家研究基金会;

关键词：

SINGLET MOLECULAR-OXYGEN; PHOTOSENSITIZED OXIDATION; PHOTOREDOX CATALYSIS; CARBONYL-COMPOUNDS; ORGANIC SULFIDES; SUPEROXIDE ION; SULFOXIDES; MECHANISM; REARRANGEMENT; PERSULFOXIDE;

D O I：

10.1021/acs.orglett.0c01399

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The oxidative cleavage reaction of the C-S bond using singlet oxygen is challenging because of its uncontrollable nature. We have developed a novel method for the singlet-oxygen-mediated selective C-S bond cleavage reaction using silver(II)-ligand complexes. Visible-light-induced silver catalysis enables the controlled oxidative cleavage of benzyl thiols to afford carbonyl compounds, such as aldehydes or ketones, which are important synthetic components.

引用

收藏

页码：4395 / 4399

页数：5

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