Facile synthesis and characterization of a novel thiophene-fused polycyclic aromatics based on pyrene

被引：8
作者：
Duan, Zong Fan [1 ,2 ]
Yang, Zhi Gang [3 ]
Liu, Dong Jie [2 ]
Cai, Li [1 ]
Hoshino, Daiki [1 ]
Morita, Tsuyoshi [1 ]
Zhao, Gao Yang [2 ]
Nishioka, Yasushiro [1 ]
机构：
[1] Nihon Univ, Coll Sci & Technol, Chiba 2748501, Japan
[2] Xian Univ Technol, Sch Mat Sci & Engn, Xian 710048, Peoples R China
[3] Nihon Univ, Coll Pharm, Chiba 2748555, Japan
来源：
CHINESE CHEMICAL LETTERS | 2011年 / 22卷 / 07期
关键词：
Pyrene; Thiophene; Stille coupling reaction; Oxidative cyclization; OXIDATIVE CYCLIZATION; TRANSISTORS;
D O I：
10.1016/j.cclet.2010.12.054
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel large thiophene-fused polycyclic aromatics 1 based on pyrene 5 has been synthesized, and its structure was confirmed by H-1 NMR, C-13 NMR, MS, UV vis and elemental analysis. The key steps of the synthesis involved the Stille cross-coupling reaction and followed by selective beta-beta oxidative cyclization of pendant thienyl rings by FeCl3 under mild conditions. (C) 2011 Zong Fan Duan. Published by Elsevier B.V. on behalf of Chinese Chemical Society. All rights reserved.
引用
收藏
页码：819 / 822
页数：4
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