Generation of nanocellular foams from ABS terpolymers

被引:23
作者
Forest, C. [1 ]
Chaumont, P. [1 ]
Cassagnau, P. [1 ]
Swoboda, B. [2 ]
Sonntag, P. [2 ]
机构
[1] Univ Lyon, CNRS UMR 5223, IMP, F-69622 Villeurbanne, France
[2] HUTCHINSON Res Ctr, F-45120 Chalette Sur Loing, France
关键词
ABS terpolymer; Carbon dioxide; Nanofoam; Morphology; CARBON-DIOXIDE; BUBBLE-GROWTH; BLOCK-COPOLYMERS; POLYMER; DIFFUSION; EXPANSION; SORPTION; SYSTEMS; STATE; CO2;
D O I
10.1016/j.eurpolymj.2014.11.006
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
ABS nano-cellular foams have been produced using a gaseous CO2 foaming process. ABS materials have been investigated in this study because of their specific morphologies, which can increase the nuclei density by creating heterogeneous nucleation near the interfaces between acrylonitrile-styrene and butadiene phases during the foaming process. This study focuses on the foaming of different ABS materials with a batch process using gaseous CO2 and presents the influence of the initial microstructures of ABS materials on their final foam structures. In specific cases, depending on initial ABS microstructures and also on foaming conditions, nano-cellular materials have been produced with foam double structures and effective porosity with 100 nm diameter open cells. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码:209 / 220
页数:12
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