Biogenic corrosion inhibitor on mild steel protection in concentrated HCl medium

被引:25
|
作者
Krishnan, Muthukumar [1 ,2 ,5 ]
Subramanian, Harinee [2 ]
Dahms, Hans-Uwe [3 ,4 ,6 ]
Sivanandham, Vignesh [1 ]
Seeni, Palanichamy [5 ]
Gopalan, Subramanian [5 ]
Mahalingam, Ashok [2 ]
Rathinam, Arthur James [1 ]
机构
[1] Bharathidasan Univ, Dept Marine Sci, Tiruchirappalli 620024, Tamil Nadu, India
[2] NIT, Dept Phys, Tiruchirappalli 620015, Tamil Nadu, India
[3] Kaohsiung Med Univ, Dept Biomed Sci & Environm Biol, 100,Shin Chuan 1st Rd, Kaohsiung 80708, Taiwan
[4] Kaohsiung Med Univ, Res Ctr Environm Med, 100,Shin Chuan 1st Rd, Kaohsiung 80708, Taiwan
[5] Electrochem Res Inst CECRI, Unit Cent, OPMEC, Tuticorin 628004, Tamil Nadu, India
[6] Natl Sun Yat Sen Univ, Dept Marine Biotechnol & Resources, 70 Lienhai Rd, Kaohsiung 80424, Taiwan
来源
SCIENTIFIC REPORTS | 2018年 / 8卷
关键词
ANTIMICROBIAL ACTIVITY; MARINE-BACTERIA; EXTRACTS; MACROALGAE; BIOFILMS; DIATOM; ALGAE; ACID;
D O I
10.1038/s41598-018-20718-1
中图分类号
O [数理科学和化学]; P [天文学、地球科学]; Q [生物科学]; N [自然科学总论];
学科分类号
07 ; 0710 ; 09 ;
摘要
Turbinaria ornata (TO) extract was tested as green corrosion inhibitor on mild steel (MS) coupons in conc. HCl medium with an efficiency of 100% at 25 g l(-1) during 5 min exposure. Antibacterial efficacy performed against 16 S rDNA identified marine biofilming bacteria (MBB) and human pathogenic bacteria (HPB). Maximum inhibition growth was 16 mm on MBB observed in Bacillus megaterium (MBF14 - AB894827) and 20 mm on HPB in Escherichia coli (B5 - NCIM 2931). Similarly, minimum of 10 mm on MBB witnessed in Pseudomonas sp., (MBF9 - AB894829). Toxicity studies proved 50.0% LC50 at 500 mu g ml(-1) in 24 hrs, whereas Balanus amphitrite resulted in 100% mortality within 12 hrs. Results including weight loss, potentiodynamic polarization and electrochemical impedance spectroscopy, FT-IR and GC-MS confirm 10-Octadecaonic acid as a major corrosion inhibitor from T. ornata and is discovered as a novel antifoulant. Anticorrosion formulation will become available soon.
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页数:16
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