Separation and analysis of triazine herbcide residues by capillary electrophoresis

被引:35
作者
Elbashir, Abdalla A. [1 ]
Aboul-Enein, Hassan Y. [2 ]
机构
[1] Univ Khartoum, Dept Chem, Fac Sci, Khartoum 11115, Sudan
[2] Natl Res Ctr, Pharmaceut & Drug Ind Res Div, Pharmaceut & Med Chem Dept, Cairo 12311, Egypt
关键词
triazine; herbicides; capillary electrophoresis; MEKC; CEC; SOLID-PHASE EXTRACTION; HIGH-PERFORMANCE LIQUID; MICELLAR ELECTROKINETIC CHROMATOGRAPHY; HYDROXY-S-TRIAZINES; ZONE-ELECTROPHORESIS; MASS-SPECTROMETRY; WATER SAMPLES; DEGRADATION-PRODUCTS; HERBICIDE RESIDUES; ATRAZINE;
D O I
10.1002/bmc.3381
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
Triazines are widely used in agriculture around the world as selective pre- and post-emergence herbicides for the control of broad leaf and grassy weeds. With high toxicity and persistence, triazines can contaminate the environment and crops, so the development of rapid and sensitive methods for the determination of different triazines is necessary. Capillary electrophoresis comprises a group of techniques used to separate chemical mixtures. Analytical separation is based on different electrophoretic mobilities. This review focuses on the analysis of triazine herbicides with different modes of capillary electrophoresis, including capillary zone electrophoresis, micellar electrokinetic capillary electrophoresis, capillary electrochromatography and nonaqueous capillary electrophoresis. Determinations of triazines in various matrices such as surface water, groundwater, vegetables, soil and grains are emphasized. Copyright (c) 2014 John Wiley & Sons, Ltd.
引用
收藏
页码:835 / 842
页数:8
相关论文
共 87 条
[1]   Atrazine biodegradation to deisopropylatrazine and deethylatrazine in coastal sediments of different land uses [J].
Aelion, CM ;
Mathur, PP .
ENVIRONMENTAL TOXICOLOGY AND CHEMISTRY, 2001, 20 (11) :2411-2419
[2]   Capillary electrochromatography with monolithic silica column: I. Preparation of silica monoliths having surface-bound octadecyl moieties and their chromatographic characterization and applications to the separation of neutral and charged species [J].
Allen, D ;
El Rassi, Z .
ELECTROPHORESIS, 2003, 24 (03) :408-420
[3]   ATRAZINE AND OTHER S-TRIAZINE HERBICIDES IN LAKES AND IN RAIN IN SWITZERLAND [J].
BUSER, HR .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1990, 24 (07) :1049-1058
[4]   Liquid-liquid extraction assisted by a carbon nanoparticles interface. Electrophoretic determination of atrazine in environmental samples [J].
Caballero-Diaz, Encarnacion ;
Simonet, Bartolome ;
Valcarcel, Miguel .
ANALYST, 2013, 138 (20) :5913-5919
[5]   ONLINE PRECONCENTRATION OF TRIAZINE HERBICIDES WITH TANDEM OCTADECYL CAPILLARIES-CAPILLARY ZONE ELECTROPHORESIS [J].
CAI, J ;
ELRASSI, Z .
JOURNAL OF LIQUID CHROMATOGRAPHY, 1992, 15 (6-7) :1179-1192
[6]   Comparison of a non-aqueous capillary electrophoresis method with high performance liquid chromatography for the determination of herbicides and metabolites in water samples [J].
Carabias-Martinez, R. ;
Rodriguez-Gonzalo, E. ;
Miranda-Cruz, E. ;
Dominguez-Alvarez, J. ;
Hernandez-Mendez, J. .
JOURNAL OF CHROMATOGRAPHY A, 2006, 1122 (1-2) :194-201
[7]  
Carabias-Martínez R, 2002, ELECTROPHORESIS, V23, P494, DOI 10.1002/1522-2683(200202)23:3<494::AID-ELPS494>3.0.CO
[8]  
2-P
[9]   Analysis of triazines by capillary electrochromatography/electrospray ionization-mass spectrometry using a low-flow sheath liquid interface [J].
Chang, Chia-Hao ;
Chen, Chao-Jung ;
Chuang, Yu-Chieh ;
Her, Guor-Rong .
ELECTROPHORESIS, 2006, 27 (21) :4303-4311
[10]   Determination of nicotinyl pesticide residues in vegetables by micellar electrokinetic capillary chromatography with quantum dot indirect laser-induced fluorescence [J].
Chen, Guan-Hua ;
Sun, Juan ;
Dai, Yong-Jia ;
Dong, Min .
ELECTROPHORESIS, 2012, 33 (14) :2192-2196